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Studies on Separation Analysis Based on Dynamic Flow of Solvent Clusters

Studies on Separation Analysis Based on Dynamic Flow of Solvent Clusters
基于溶剂团簇动态流动的分离分析研究
批准号:
21550086
负责人:
TABATA Masaaki
金额:
$3.08万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (C)
财政年份:
2009
资助国家:
日本
项目状态:
已结题
起止时间:
2009 至 2011

项目摘要

项目成果

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相关文献

中文摘要
翻译
在微观尺度上观察水与水溶性有机溶剂的混合物的溶剂结构,该混合物不是均相的而是非均相的,其中水和有机溶剂分子自组装以分别形成水和有机溶剂的簇。当化合物溶解在混合溶剂中时,水溶性化合物溶解在水溶剂簇中,有机化合物溶解在有机溶剂簇中。在混合溶剂中,两种组分(可溶于水和可溶于有机溶剂)自动分离。基于这一思想,建立了一种新的分离方法,该方法不需要分离柱,只需一根小毛细管。
英文摘要
Looking at solvent structure on a micro scale for the mixture of water with water-soluble organic solvent, the mixture is not homogeneous but heterogeneous, where water and organic solvent molecules self-assemble to form clusters of water and organic solvents separately. When compounds are dissolved in the mixed solvents, water-soluble compounds dissolve in water solvent clusters and organic compounds in organic solvent clusters. Two components(soluble in water and soluble in organic solvent) are automatically separated in the mixed solvent. Based on this idea new separation method has been established without a separation column by using a small capillary tube.
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会议论文
錯体の溶液化学
配合物的溶液化学
DOI: --
发表时间: 2012
期刊:
影响因子: --
作者: [H. Muraoka, T. Endo, S. Ogawa, 山口敏男]
通讯作者: 山口敏男
DOI: 10.1142/s1088424612004550
发表时间: 2012
期刊: Journal of Porphyrins and Phthalocyanines
影响因子: 1.5
作者: [Nanda Gunawardhana, Shingo Homi, Masaaki Tabata, Md. Kutubi and Masaaki Tabata]
通讯作者: Md. Kutubi and Masaaki Tabata
Capillary flow separation using aqueous mixed solvents of ionic liquids
使用离子液体的水性混合溶剂的毛细管流分离
DOI: --
发表时间: 2010
期刊:
影响因子: --
作者: [徐中其, 荒井昭博, 廣川健, M. Tabata ; K. Fujii ; C. Thiraporn]
通讯作者: M. Tabata ; K. Fujii ; C. Thiraporn
Solvation of the Amphiphilic Diol Molecule in Aliphatic Alcohol-Water and Fluorinated Alcohol-Water Solutions
两亲二醇分子在脂肪醇-水和氟化醇-水溶液中的溶剂化
DOI: 10.1021/jp9097414
发表时间: 2010
期刊: J. Phys. Chem. B
影响因子: 3.3
作者: [T. Takamuku, M. Tanaka, T. Sako, T. Shimomura, K. Fujii, R. Kanzaki, and M.Takeuchi]
通讯作者: and M.Takeuchi
共 28 条
    Simultaneous Determination of the Oxidation State of Sulfur in the Asbestos Decomposition
    • 批准号:
      24550103
    • 项目类别:
      Grant-in-Aid for Scientific Research (C)
    • 资助金额:
      $3.49万
    • 财政年份:
      2012
    • 负责人:
      TABATA Masaaki
    • 依托单位:
    Study on Solvent Micro-Cluster Extraction and Separation Method
    • 批准号:
      19350041
    • 项目类别:
      Grant-in-Aid for Scientific Research (B)
    • 资助金额:
      $11.07万
    • 财政年份:
      2007
    • 负责人:
      TABATA Masaaki
    • 依托单位:
    Study on a New Open Tubular Capillary Liquid Chromatography(OTCLC) System Based on Micro-Phase Separation of Mixed Solvents
    • 批准号:
      15350046
    • 项目类别:
      Grant-in-Aid for Scientific Research (B)
    • 资助金额:
      $8.06万
    • 财政年份:
      2003
    • 负责人:
      TABATA Masaaki
    • 依托单位:
    Formation and Mechanism of Alkali Metal Porphyrins and their Application to Analytical Chemistry
    • 批准号:
      08454238
    • 项目类别:
      Grant-in-Aid for Scientific Research (B)
    • 资助金额:
      $5.5万
    • 财政年份:
      1996
    • 负责人:
      TABATA Masaaki
    • 依托单位:
    海外基金