Elucidation and application of the multifunctional expression mechanism of the environment-oriented optical active hybrid complex

我们找到了一种特定的方法来立体选择性地制备光学活性多核配合物，另一方面，它可以通过使用其他配合物来获得不同的形成比。此外，还阐明了当我们改变配体的取代基时，我们很容易改变多核结构。我们能够获得关于环境响应型络合物中手性选择性的附加因素的知识。由于这些产品的立体专一性和溶解性存在显著差异，因此被认为是作为有用材料的价值上升。这些研究内容都是针对环境响应型光学活性多核配合物的发展，经过一段时间的持续考察，我们希望利用这个系统来扩大功能表达。

We found a specific method to prepare the optical active polynuclear complexes stereoselectively, and on the other hand, it could obtain a various formation ratio by the use of other complexes. Furthermore, it is clarified that we could easily change the polynuclear structures when we changed the substituent of the ligands. We were able to get the knowledge concerning the additional factor for the chiral selectivity in the environmental response type complexes. Since there were remarkable differences between the stereospecificity and the solubility in those products, it is thought that the value as the useful materials are risen. These study contents, which aim at the development of the environmental response type optical active polynuclear complexes, continually examine after a grant period, and we want to enlarge the functional expression using this system.