Development of Coupling Reactions Using Electrogenerated Active Organometallic

研究的目的是利用电生成的有机金属物种的新型偶联反应的发展。我们研究了电化学生成的钯物种催化的几个偶联反应。在研究过程中，我们发现助氧化剂和助催化剂的选择对于偶联反应的控制非常重要，溶剂的极性也很重要。通过对这些因素的优化，我们成功地开发了高效的偶联反应，得到了多种联芳和二炔衍生物。

The objective of research is the development of novel coupling reactions using electrogenerated organometallic species. We investigated several coupling reactions catalyzed by electrochemically generated palladium species. During the course of the study, we found that the choice of a co-oxidant and co-catalyst was highly significant for the control of the coupling reactions, and the polarity of the solvent was also important. After the optimization of these factors, we have achieved the development of the efficient coupling reactions leading to a wide variety of biaryls and diyne derivatives.