Fluorine probehead and accessories for solid-state NMR spectrometer

该提案要求为拉瓦尔大学化学系购买Bruker Avance 400固态NMR光谱仪的三重共振氟探头提供资金。该探头将允许测量具有质子去耦的固态19 F NMR谱。此外，几个三重共振实验1H/19 F/X（X = N-C）将与该设备访问。该探头将被M。Auger，F. Kleitz，J. F. Morin，T. Ollevier，J. F.帕奎因和A.M.里奇研究项目的例子，将与该设备进行调查，包括使用氟化脂质作为膜拓扑结构的探针，肽结构的测定和膜中的低聚化，镧系氟化物纳米粒子的研究，在固态工作的纳米机器的特性，功能介孔和中孔材料的开发和新的刘易斯酸催化剂的合成。

This proposal requests funding for the purchase of a triple resonance fluorine probehead for the Bruker Avance 400 solid-state NMR spectrometer in the Department of Chemistry at Université Laval. This probehead will allow the measurement of solid-state 19F NMR spectra with proton decoupling. In addition, several triple resonance experiments 1H/19F/X (X = N-C) will be accessible with this equipment. This probehead will be used extensively by the students and postdoctoral fellows of the research groups of M. Auger, F. Kleitz, J.-F. Morin, T. Ollevier, J.-F. Paquin and A.M. Ritcey. Examples of research projects that will be investigated with this equipment include the use of fluorinated lipids as probes of membrane topology, the determination of peptide structure and oligomerization in membranes, the study of lanthanide fluoride nanoparticles, the characterization of nanomachines working in the solid-state, the development of functional mesostructured and mesoporous materials and the synthesis of new Lewis acid catalysts.