Magnetic-electric behaviors in BiFeO3 films grown on LaNiO3-buffered Si substrate

Magnetic-electric behaviors in BiFeO3 films grown on LaNiO3-buffered Si substrate
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LaNiO3 缓冲 Si 衬底上生长的 BiFeO3 薄膜的磁电行为

DOI:
10.1063/1.3240327
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发表时间:
2009-10
影响因子:
3.2
通讯作者:
C. W. Nan
C. W. Nan
中科院分区:
物理与天体物理3区
文献类型:
--
作者:
Y. Wang;Z. Li;Y. H. Lin;C. W. Nan

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采用改进的化学方法在LaNiO_3缓冲硅衬底上生长了不同厚度和不同晶向的BiFeO_3薄膜。在铁电行为中观察到显著的尺寸效应,由于退偏效应和BiFeO_3薄膜的微观结构的综合作用,厚度越厚的薄膜表现出更大的极化值。高分辨电子显微镜显示BiFeO_3薄膜呈现复杂的应变状态,由反平行自旋倾斜引起的净磁矩在较厚的薄膜中无序排列,呈现自旋玻璃态;而在较薄的BiFeO_3薄膜中,无序自旋转变为有序排列的铁磁行为。因此,随着薄膜厚度的变化,存在铁电和磁性行为之间的竞争。此外,在磁场感应电压为3.5VOe左右的BiFeO_3薄膜中观察到了磁电耦合现象。
BiFeO3 films with different thicknesses and crystallographic orientations were grown on LaNiO3-buffered Si substrates via a modified chemical route. Remarkable size effect in ferroelectric behavior was observed with thicker films exhibiting a larger polarization value, due to combined depolarization effect and microstructure of the BiFeO3 films. High resolution transmission electron micrograph revealed a complex strain state in the BiFeO3 films, and the net magnetic moment induced by the canting of the antiparallel spins was arranged in disorder in thicker films, presenting a spin-glass state; while in the thinner BiFeO3 films, the disorder spins turned to be orderly arranged to induce a ferromagnetic behavior. Thus there exists a competition between ferroelectric and magnetic behaviors as film thickness changes. Furthermore, magnetoelectric coupling was observed in the BiFeO3 films with a magnetic-field-induced electrical voltage of around 3.5 μV/Oe.
通过拉曼光谱和压电力显微镜研究 BiFeO3 薄膜的位点修饰
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