Recent progress on cyano-bridged transition-metal-based single-molecule magnets and single-chain magnets
Recent progress on cyano-bridged transition-metal-based single-molecule magnets and single-chain magnets
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氰基桥联过渡金属基单分子磁体和单链磁体的最新进展
DOI：
10.1016/j.ccr.2020.213617
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发表时间：
2021-02
影响因子：
20.6
通讯作者：
Xian-He Bu
中科院分区：
文献类型：
--
作者：
Jin-Hua Wang;Zhao-Yang Li;Masahiro Yamashita;Xian-He Bu
新型功能性分子基磁性材料，特别是普鲁士蓝家族的一些成员，在过去的几十年中获得了极大的关注，因为它们可以有益地用于各种科学领域。本文综述了氰基桥联过渡金属单分子磁体和单链磁体的研究进展。氰化物配体对过渡金属有很强的亲和力，是一种常用的桥连配体，根据共配体的类型，可以构建各种分子磁性材料。本文主要介绍了结构拓扑学和相应的自组织模型或自组织模型的研究。第一部分简要介绍了SMM和SCM行为以及构建各种磁性材料的重要原则和策略。其余各节概述了近年来报告的重大成就。在最后一节中，我们总结了氰尿酸盐为基础的SMM和SCM的前景，并提供了一些新的见解，这一有前途的领域。
Novel functional molecular-based magnetic materials, especially some members of the Prussian blue family, have gained significant attention over the past few decades as they can be used beneficially in a variety of scientific fields. Herein, we survey the latest developments in cyano-bridged transition-metal-based single-molecule magnets (SMMs) and single-chain magnets (SCMs) research. The cyanide ligand, which has a strong affinity for transition metals, is a popular bridging ligand to construct a variety of molecular-magnetic materials, depending on the type of co-ligand. This review mainly focuses on research into structural topologies and the corresponding SMMs or SCMs. The first section provides a brief introduction into SMM and SCM behavior and important principles and strategies for constructing diverse magnetic materials. The remaining sections provide overviews of significant achievements reported in recent years. In the final section we conclude by presenting perspectives on cyanometallate-based SMMs and SCMs and by providing some new insight into this promising area.
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影响因子：
4.9
作者：
Jia Li;Ying Guo;Hong-Ru Fu;Jian Zhang;Rong-Bin Huang;Lan-Sun Zheng;J. Tao
通讯作者：
Jia Li;Ying Guo;Hong-Ru Fu;Jian Zhang;Rong-Bin Huang;Lan-Sun Zheng;J. Tao
影响因子：
46.2
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Yong-Fei Zeng;Xin Hu;Fu‐Chen Liu;X. Bu
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Yong-Fei Zeng;Xin Hu;Fu‐Chen Liu;X. Bu
影响因子：
4.6
作者：
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通讯作者：
Vostrikova, Kira E.
影响因子：
3.8
作者：
Liang Zhao;Yan-juan Zhang;Jixiang Hu;Cheng–Qi Jiao;Junli Wang;Chunying Duan;Tao Liu
通讯作者：
Liang Zhao;Yan-juan Zhang;Jixiang Hu;Cheng–Qi Jiao;Junli Wang;Chunying Duan;Tao Liu
基于八氰钨酸盐的单链磁体，对氰化物具有最高的能垒
影响因子：
4.6
作者：
Wei RM;Cao F;Li J;Yang L;Han Y;Zhang XL;Zhang Z;Wang XY;Song Y
通讯作者：
Song Y