Vapor Transport Sintering of Porous Calcium Phosphate Ceramics

Vapor Transport Sintering of Porous Calcium Phosphate Ceramics
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多孔磷酸钙陶瓷的气相传输烧结

DOI:
10.1111/j.1551-2916.2012.05121.x
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发表时间:
2012
影响因子:
3.9
通讯作者:
Kleebe
Kleebe
中科院分区:
材料科学2区
文献类型:
--
作者:
Schlosser;Kleebe

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Vapor transport sintering (VTS) of calcium phosphates in various reactive atmospheres was investigated as a new fabrication method for ceramic scaffolds with fully interconnected porosity. Experiments were carried out for two different starting compositions—β‐tricalcium phosphate (β‐TCP) and biphasic calcium phosphate (BCP)—within various halide atmospheres and in water vapor. During the nondensifying VTS process, grain and pore size increase simultaneously although the interconnectivity of the pores is retained. Successful VTS is possible in the presence of several halide acids (HCl, HBr) and solid chlorides (MgCl2, CaCl2, AgCl). At elevated temperatures, sufficient amounts of volatile species are formed to sustain material transport through evaporation and condensation. The resulting microstructure and phase composition are both adjustable by choosing appropriate precursor materials, additives and process parameters. Furthermore, the use of AgCl as a sintering additive both facilitates VTS and the condensation of finely dispersed Ag particles on the scaffold's surface, which may lend antibacterial properties to the implant material.
在 HCl 气氛中烧结 TiO2
DOI: 10.1111/j.1151-2916.1987.tb04919.x
发表时间: 1987
影响因子: 3.9
作者:
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期刊: THIN SOLID FILMS
影响因子: 2.1
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