Synthesis of a self-assembled copper(II) metallo-rectangle with a guanosine-substituted terpyridine.

Synthesis of a self-assembled copper(II) metallo-rectangle with a guanosine-substituted terpyridine.
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用鸟苷取代的三联吡啶合成自组装铜(II)金属矩形。

DOI:
10.1039/c3dt51845k
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发表时间:
2013
期刊:
2003)
影响因子:
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通讯作者:
Ghosh S
Ghosh S
中科院分区:
--
文献类型:
--
作者:
Ghosh S

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报道了三吡啶-鸟苷配体的合成及其与铜(II)的反应,得到了一个新的[2 + 2]金属矩形。用x -射线单晶衍射对金属矩形进行了表征,其结构表现出分子内两个三吡啶部分之间明显的π -π堆叠相互作用。这促使我们研究新的二铜(II)组件的磁性能,它在固态中表现出铁磁相互作用。
The synthesis of a terpyridine–guanosine ligand and its reaction with copper(II) to yield a new [2 + 2] metallo-rectangle is reported. The metallo-rectangle was characterized by single crystal X-ray diffraction and the structure showed significant intramolecular π–π stacking interactions between the two terpyridine moieties of the molecule. This prompted us to investigate the magnetic properties of the new di-copper(II) assembly which displayed ferromagnetic interactions in the solid state.
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