Synthesis of a self-assembled copper(II) metallo-rectangle with a guanosine-substituted terpyridine.
Synthesis of a self-assembled copper(II) metallo-rectangle with a guanosine-substituted terpyridine.
复制标题
用鸟苷取代的三联吡啶合成自组装铜(II)金属矩形。
DOI:
10.1039/c3dt51845k
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发表时间:
2013
期刊:
影响因子:
--
通讯作者:
Ghosh S
中科院分区:
文献类型:
--
作者:
Ghosh S
The synthesis of a terpyridine–guanosine ligand and its reaction with copper(II) to yield a new [2 + 2] metallo-rectangle is reported. The metallo-rectangle was characterized by single crystal X-ray diffraction and the structure showed significant intramolecular π–π stacking interactions between the two terpyridine moieties of the molecule. This prompted us to investigate the magnetic properties of the new di-copper(II) assembly which displayed ferromagnetic interactions in the solid state.
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