Supramolecular coordination: self-assembly of finite two- and three-dimensional ensembles.
Supramolecular coordination: self-assembly of finite two- and three-dimensional ensembles.
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DOI：
10.1021/cr200077m
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发表时间：
2011-11-09
期刊：
影响因子：
62.1
通讯作者：
Stang, Peter J.
中科院分区：
文献类型：
--
作者：
Chakrabarty, Rajesh;Mukherjee, Partha Sarathi;Stang, Peter J.
在过去的几十年里，超分子化学的魅力导致了越来越多的优雅和复杂的功能结构的合成，其尺寸接近纳米尺度。今天，它已经成长为一个成熟的现代科学领域，与许多学科的接口提供了宝贵的机会，跨越边界内部和之间的化学，物理学和生物学领域。这种化学反应一直受到合成化学家的关注，部分原因是超分子具有迷人的物理和化学性质以及复杂多样的美观结构。对于寻求设计具有不寻常的传感，磁性，光学和催化性能的新型分子材料的科学家，以及研究生物分子结构和功能的研究人员，超分子化学提供了无限的可能性。因此，它超越了传统的科学划分界限，代表了一个高度跨学科的领域。在20世纪60年代早期，Pedersen、1 Lehn、2和Cram 3分别发现了“冠醚”、“穴状配体”和“球状配体”，这使得人们认识到，可以使小的互补分子通过非共价相互作用（如氢键、荷电电荷、供体和受体）相互识别，
Fascination with supramolecular chemistry over the past few decades has led to the synthesis of an ever-increasing number of elegant and intricate functional structures with sizes that approach nanoscopic dimensions. Today, it has grown into a mature field of modern science whose interfaces with many disciplines have provided invaluable opportunities for crossing boundaries both inside and between the fields of chemistry, physics, and biology. This chemistry is of continuing interest for synthetic chemists, partly because of the fascinating physical and chemical properties and the complex and varied aesthetically pleasing structures that supramolecules possess. For scientists seeking to design novel molecular materials exhibiting unusual sensing, magnetic, optical, and catalytic properties, and for researchers investigating the structure and function of biomolecules, supramolecular chemistry provides limitless possibilities. Thus, it transcends the traditional divisional boundaries of science and represents a highly interdisciplinary field. In the early 1960s, the discovery of “crown ethers”,“cryptands”, and “spherands” by Pedersen, 1 Lehn, 2 and Cram3, respectively, led to the realization that small, complementary molecules can be made to recognize each other through noncovalent interactions such as hydrogen bonding, chargeÀcharge, donorÀacceptor,
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影响因子：
16.6
作者：
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通讯作者：
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影响因子：
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作者：
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影响因子：
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作者：
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影响因子：
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作者：
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