Visible-light promoted three-component tandem reaction to synthesize difluoromethylated oxazolidin-2-imine.
Visible-light promoted three-component tandem reaction to synthesize difluoromethylated oxazolidin-2-imine.
复制标题
可见光促进三组分串联反应合成二氟甲基恶唑烷-2-亚胺
作者：
以芳基烯丙基胺、2-BTSO 2CF 2 H（BT =苯并噻唑）和异氰酸酯为原料，通过可见光催化三组分串联反应合成了二氟甲基恶唑烷-2-亚胺。该方法具有反应条件温和、官能团耐受性好等特点，反应机理得到了实验证实和量子化学计算的解释。可见光促进三组分串联反应。
An effective synthetic method to achieve difluoromethylated oxazolidin-2-imine has been developed via visible-light promoted three-component tandem reaction of aryl allylamines, 2-BTSO2CF2H (BT = Benzothiazole) and isocyanates. This method features mild reaction conditions and good functional group tolerance, and the reaction mechanism was confirmed by experiments and interpreted by quantum chemical calculations. Visible-light promoted three-component tandem reaction.
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