Highly oriented 1-D ZnO nanorod arrays on zinc foil: Direct growth from substrate, optical properties and photocatalytic activities

Highly oriented 1-D ZnO nanorod arrays on zinc foil: Direct growth from substrate, optical properties and photocatalytic activities
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锌箔上高度定向的一维 ZnO 纳米棒阵列:从基底直接生长、光学特性和光催化活性

DOI:
10.1021/jp7113175
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发表时间:
2008-04
影响因子:
3.7
通讯作者:
Lu, Guang
Lu, Guang
中科院分区:
化学3区
文献类型:
--
作者:
Chen, Guohua;Wang, Yuxin;Quan, Xie;Li, Xinyong;Lu, Guang

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采用一种简单的低温液相法在锌片上成功地合成了高度取向的大尺寸ZnO纳米棒阵列。在这种方法中,锌箔不仅用作衬底,而且还作为锌离子源用于直接生长ZnO纳米棒阵列。X射线衍射(XRD)分析、高分辨透射电镜(HRTEM)图像和选区电子衍射(SAED)图案表明,在锌箔衬底上的ZnO纳米棒阵列的结构是单晶的,并且以纤锌矿结构沿[0001]方向生长。ZnO纳米棒阵列的光学性质通过紫外-维斯漫反射、拉曼和光致发光光谱进行表征。通过紫外光照射下降解4-氯苯酚(4-CP)测试了ZnO纳米棒阵列的光催化活性,并与Ti衬底上生长的ZnO纳米棒薄膜进行了比较,结果表明所合成的ZnO纳米棒阵列具有优异的光催化活性。
Highly oriented and large-scale ZnO nanorod arrays have been successfully synthesized on zinc foil by a simple, low-temperature, solution-phase approach. In this approach, zinc foil was used not only as a substrate but also as a zinc-ion source for the direct growth of ZnO nanorod arrays. X-ray diffraction (XRD) analysis, high-resolution TEM (HRTEM) images, and selected-area electron diffraction (SAED) patterns indicated that the structure of the ZnO nanorod arrays on the zinc foil substrate was single-crystalline and grown in the [0001] direction with a wurtzite structure. The optical properties of the ZnO nanorod arrays were characterized by UV−vis diffuse reflectance, Raman, and photoluminescence spectroscopies. The photocatalytic activity of the ZnO nanorod arrays was tested by degradation of 4-chlorophenol (4-CP) under UV light irradiation compared to that of a ZnO nanorod film grown on a Ti substrate, indicating that the as-synthesized ZnO nanorod arrays exhibit excellent photocatalytic activity.
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