Remarkable piezoelectricity and stable high-temperature dielectric properties of quenched BiFeO3-BaTiO3 ceramics

Remarkable piezoelectricity and stable high-temperature dielectric properties of quenched BiFeO3-BaTiO3 ceramics
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淬火BiFeO3-BaTiO3陶瓷具有显着的压电性和稳定的高温介电性能

DOI:
10.1111/jace.15079
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发表时间:
2017-12
影响因子:
3.9
通讯作者:
Chen Jianguo
Chen Jianguo
中科院分区:
材料科学2区
文献类型:
--
作者:
Li Qiang;Wei Jianxin;Tu Tinglong;Cheng Jinrong;Chen Jianguo

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研究了淬火工艺对Mn变质0.71BiFeO3-0.29BaTiO3陶瓷(BF-BT-xmol%Mn)介电、铁电和压电性能的影响。淬火改善了BF-BT-xmol%Mn陶瓷的介电、铁电和压电性能,尤其是对BF-BT-0.3mol%Mn陶瓷的改善更为明显。急冷BF-BT-0.3mol%Mn陶瓷在500 °C时的介电损耗tanδ仅为0.28,是缓冷陶瓷的一半。淬火后的BF-BT- 0.3mol%Mn陶瓷的剩余极化强度Pr提高到21 μC/cm ~ 2。值得注意的是,淬火BF-BT-0.3mol%Mn陶瓷的压电常数d33高达191 pC/N,TC为530 °C,表现出优异的相容性。在合适的电场范围内,BF-BT-xmol%Mn系陶瓷的电性能符合瑞利定律。瑞利定律的结果表明,淬火的BF-BT-xmol%Mn陶瓷的介电和压电响应的外部贡献大于未淬火的陶瓷。这些结果表明,淬火BF-BT-xmol%Mn陶瓷是有希望的候选人,高温压电器件。 本文受版权保护。All rights reserved.
Effects of quenching process on dielectric, ferroelectric and piezoelectric properties of 0.71BiFeO3-0.29BaTiO3 ceramics with Mn modification (BF-BT-xmol%Mn) were investigated. The dielectric, ferroelectric and piezoelectric properties of BF-BT-xmol%Mn were improved by quenching, especially to the BF-BT-0.3mol%Mn ceramics. The dielectric loss tanδ of quenched BF-BT-0.3mol%Mn ceramics was only 0.28 at 500 °C, which was half of the slow cooling one. Meanwhile, the remnant polarization Pr of quenched BF-BT- 0.3mol%Mn ceramics increased to 21 μC/cm2. It was notable that the piezoelectric constant d33 of quenched BF-BT-0.3mol%Mn ceramics reached up to 191 pC/N, while the TC was 530 °C, showing excellent compatible properties. The BF-BT-xmol%Mn system ceramics showed to obey the Rayleigh law within suitable field regions. The Rayleigh law results indicated that the extrinsic contributions to the dielectric and piezoelectric responses of quenched BF-BT-xmol%Mn ceramics were larger than the un-quenched ceramics. These results presented that the quenched BF-BT-xmol%Mn ceramics were promising candidates for high-temperature piezoelectric devices. This article is protected by copyright. All rights reserved.
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