Impact of solar irradiance intensity and temperature on the performance of compensated crystalline silicon solar cells

Impact of solar irradiance intensity and temperature on the performance of compensated crystalline silicon solar cells
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太阳辐照强度和温度对补偿晶体硅太阳能电池性能的影响

DOI:
10.1016/j.solmat.2014.06.018
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发表时间:
2014-09
影响因子:
6.9
通讯作者:
Duanlin Que
Duanlin Que
中科院分区:
材料科学2区
文献类型:
--
作者:
Chengquan Xiao;Xuegong Yu;Deren Yang;Duanlin Que

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具有硼(B)和磷(P)补偿特性的低成本升级冶金级硅(UMG-Si)是一种新型光伏材料。本文介绍了太阳辐照强度和温度对补偿晶体硅太阳电池性能的影响。对于相同的额定输出功率,补偿晶体硅太阳能电池在低辐照强度下产生的电力比参考硅太阳能电池少,这是由于补偿硅中高浓度的B-O络合物导致载流子寿命的强烈注入依赖性。然而,在高温下,补偿晶体硅太阳能电池比参考硅太阳能电池产生更多的电力,这主要源于补偿硅中的少数电子迁移率的较低温度变化。这表明,补偿硅太阳电池将更适合于高辐照应用,往往包含高辐照强度和高温。这些结果对于了解基于UMG-Si的太阳能电池的实际户外性能及其在光伏(PV)行业中的应用具有重要意义。
Low-cost upgraded metallurgical grade silicon (UMG-Si) with inherent boron (B) and phosphorus (P) compensation is a novel material for photovoltaic application. This paper presents the impact of solar irradiance intensity and temperature on the performance of compensated crystalline silicon solar cells. For the same rated output power, compensated crystalline silicon solar cells generate less electricity than the reference silicon solar cells at low irradiance intensity, owing to the strong injection dependence of the carrier lifetime due to high concentration of B–O complexes in compensated silicon. However, at high temperature, compensated crystalline silicon solar cells generate more electricity than the reference silicon solar cells, which mainly originates from the lower temperature-variation of the minority electron mobility in compensated silicon. It suggests that compensated silicon solar cells will be more appropriate for high irradiation application, which often contains high irradiance intensity and high temperature. These results are of great significance for understanding the actual outdoor performance of the solar cells based on the UMG-Si and their application in the photovoltaic (PV) industry.
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