Dissolution of solid copper in liquid tin enhanced by the liquid structural transition

Dissolution of solid copper in liquid tin enhanced by the liquid structural transition
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液体结构转变增强了固体铜在液体锡中的溶解

DOI:
10.1063/1.4885915
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发表时间:
2014-06
影响因子:
3.2
通讯作者:
Zhou, Guang-Wei
Zhou, Guang-Wei
中科院分区:
物理与天体物理3区
文献类型:
--
作者:
Qi, Xuan;Ding, Guo-Hua;Zhou, Guang-Wei

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液态金属的物理化学性质对许多工艺过程有很大的影响。在恒压下,金属液态结构的反常现象受温度的影响。研究了673 ~ 823 K温度范围内,液态Sn结构转变对固态Cu在液态Sn中溶解动力学的影响。结构转变显著影响固体Cu的溶解速率常数。相应地,液态结构转变的应用显著降低了溶解活化能和扩散表观活化能。
Physicochemical properties of liquid metals have great impact on many technological processes. Anomalies in liquid structure of metals are affected by temperature at constant pressure. This study investigated the dissolution kinetics of solid Cu in liquid Sn under the influence of structural transition of liquid Sn at temperatures varying from 673 K to 823 K. Structural transition significantly affected the dissolution rate constant of solid Cu. Correspondingly, application of liquid structural transition significantly decreased the activation energy of dissolution and the apparent activation energy of diffusion.
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