Room-temperature ferromagnetism of the amorphous Cu-doped ZnO thin films

Room-temperature ferromagnetism of the amorphous Cu-doped ZnO thin films
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非晶Cu掺杂ZnO薄膜的室温铁磁性

DOI:
10.1016/j.apsusc.2009.10.096
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发表时间:
2010-02
影响因子:
6.7
通讯作者:
Yang, Yinghu
Yang, Yinghu
中科院分区:
材料科学1区
文献类型:
--
作者:
Qi, Jing;Gao, Daqiang;Zhang, Li;Yang, Yinghu

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采用射频磁控共溅射法在玻璃基片上制备了非晶态Cu掺杂ZnO薄膜(ZnO:Cu)。磁性测量表明,非晶ZnO:Cu薄膜在室温下具有铁磁性,其饱和磁化强度远高于多晶薄膜。X射线衍射结果表明,非晶态ZnO:Cu薄膜中没有Cu 2 O相,这可能是薄膜具有高磁矩的原因。另一方面,非晶ZnO:Cu薄膜的高饱和磁化强度也可以归因于Cu在非晶ZnO溶剂中的固溶度没有限制。X射线光电子能谱研究表明,Cu以Cu ~(2+)化学状态存在。
Amorphous copper-doped ZnO thin films (ZnO:Cu) prepared on glass substrates by the radio-frequency magnetron co-sputtering have been investigated. Magnetic measurements indicated that the amorphous ZnO:Cu thin films were ferromagnetic at room temperature and the saturation magnetization was much higher than that of the polycrystalline films. X-ray diffraction results showed there was no Cu2O phase in amorphous ZnO:Cu films, which might be the reason for the high magnetic moment of the films. On the other hand, the high saturation magnetization of the amorphous ZnO:Cu films could also attribute to that there was no limit of solid solubility of Cu in amorphous ZnO solvent. The X-ray photoelectron spectroscopy study of the amorphous ZnO:Cu thin films reveal that copper was in Cu2+chemical state.
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