Effect of biphase on dielectric properties of Bi-doped lead strontium titanate thin films

Effect of biphase on dielectric properties of Bi-doped lead strontium titanate thin films
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双相对Bi掺杂钛酸铅锶薄膜介电性能的影响

DOI:
10.1016/j.jssc.2010.09.007
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发表时间:
2010-11
影响因子:
3.3
通讯作者:
Dai, J. L.
Dai, J. L.
中科院分区:
化学3区
文献类型:
--
作者:
Song, C. L.;Du, P. Y.;Tu, Y.;Weng, W. J.;Han, G. R.;Zhao, Y. L.;Li, X. T.;Dai, J. L.

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采用溶胶-凝胶法制备了掺杂不同浓度Bi的Pb0.4Sr0.6TiO3(PST)薄膜。分别通过X射线衍射(XRD)、扫描电子显微镜(SEM)和阻抗分析仪测量了这些薄膜的相状态、表面形貌和介电性能。结果表明,当x=0.15时,获得了具有最大介电常数和最小介电损耗的薄膜。当 x<0.15 时,薄膜中仅存在纯 PST 钙钛矿相。当0.2<x<0.4时,获得PST/Bi2Ti2O7双相。 x=0.67 时获得纯 Bi2Ti2O7 烧绿石相薄膜。双相薄膜具有高可调性和高品质因数(FOM)。 PST/Bi2Ti2O7双相薄膜的FOM比纯钙钛矿相或纯烧绿石相形成的薄膜高约6倍。
Pb0.4Sr0.6TiO3(PST) thin films doped with various concentration of Bi were prepared by a sol–gel method. The phase status, surface morphology and dielectric properties of these thin films were measured by X-ray diffraction (XRD), scanning electron microscopy (SEM) and impedance analyzer, respectively. Results showed that the thin films with the maximum dielectric constant and minimum dielectric loss were obtained for x=0.15. For x<0.15, only pure PST perovskite phase were in the thin films. For 0.2<x<0.4, the PST/Bi2Ti2O7biphase were obtained. The thin films with pure Bi2Ti2O7pyrochlore phase were obtained for x=0.67. The biphase thin films had high tunability and high figure of merit (FOM). The FOM of PST/Bi2Ti2O7biphase thin film was about 6 times higher than that thin films formed with pure perovskite phase or pure pyrochlore phase.
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