Persistent Luminescence in Non-Eu(2+)-Doped Compounds: A Review.

Persistent Luminescence in Non-Eu(2+)-Doped Compounds: A Review.
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DOI:
10.3390/ma6072789
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发表时间:
2013-07-12
期刊:
Materials (Basel, Switzerland)
影响因子:
--
通讯作者:
Smet PF
Smet PF
中科院分区:
其他
文献类型:
--
作者:
Van den Eeckhout K;Poelman D;Smet PF

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在过去的几十年里,对持续发光材料的研究主要集中在Eu2+掺杂的化合物上。然而,每年关于非eu2 +基材料的出版物数量也在稳步增加。到目前为止,已知的持久性荧光粉的数量已增加到200多个,其中80%以上不是基于Eu2+,而是基于固有宿主缺陷,过渡金属(锰,铬,铜等)或三价稀土(铈,铽,镝等)。本文综述了非eu2 +基持续发光材料及其余辉特性的研究进展。我们还仔细研究了一些仍然存在的挑战,例如可见光的激发性和多个发光中心之间能量转移的可能性。最后,我们总结了持久发光材料的完整描述的必要元素,以便对这些荧光粉进行更客观的比较。
During the past few decades, the research on persistent luminescent materials has focused mainly on Eu2+-doped compounds. However, the yearly number of publications on non-Eu2+-based materials has also increased steadily. By now, the number of known persistent phosphors has increased to over 200, of which over 80% are not based on Eu2+, but rather, on intrinsic host defects, transition metals (manganese, chromium, copper, etc.) or trivalent rare earths (cerium, terbium, dysprosium, etc.). In this review, we present an overview of these non-Eu2+-based persistent luminescent materials and their afterglow properties. We also take a closer look at some remaining challenges, such as the excitability with visible light and the possibility of energy transfer between multiple luminescent centers. Finally, we summarize the necessary elements for a complete description of a persistent luminescent material, in order to allow a more objective comparison of these phosphors.
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