Ultra-high temperature oxidation behavior of micro-laminated ZrC/MoSi2 coating on C/C composite

Ultra-high temperature oxidation behavior of micro-laminated ZrC/MoSi2 coating on C/C composite
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C/C复合材料微叠层ZrC/MoSi2涂层的超高温氧化行为

DOI:
10.1016/j.corsci.2017.12.034
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发表时间:
2017-12
期刊:
影响因子:
8.3
通讯作者:
Xiaohui Yin
Xiaohui Yin
中科院分区:
材料科学1区
文献类型:
--
作者:
Jingjun Xu;Tiantian Yang;Yang Yang;Yuhai Qian;Meishuan Li;Xiaohui Yin

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采用封装渗硅法和磁控溅射法在C/C复合材料表面制备了内层为SiC过渡层、外层为ZrC/MoSi 2微层状结构的防护涂层。外层总厚度为60 μm,ZrC亚层厚度为4 μm,MoSi 2亚层厚度为1 μm。超高温氧化测试在静态空气中在1800 °C下进行30分钟。涂层C/C复合材料的氧化动力学符合抛物线规律。这种有吸引力的超高温抗氧化性归因于形成的致密和无剥落的氧化膜和低的氧扩散系数的ZrCxOy。
A protective coating with transition inner layer of SiC and micro-laminated outer layer of ZrC/MoSi2was prepared by packaging siliconizing and magnetron sputtering on C/C composite. The total thickness of the micro-laminated outer layer was 60 μm, and the thicknesses of ZrC and MoSi2sublayers were 4 μm and 1 μm, respectively. Ultra-high temperature oxidation test was conducted at 1800 °C for 30 min in static air. The oxidation kinetics of coated C/C composite followed parabolic law. Such attractive ultra-high temperature oxidation resistance was attributed to the formation of a dense and spallation-free oxide scale and low oxygen diffusion coefficient of ZrCxOy.
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