An ordered array based on vapor-processed phthalocyanine nanoribbons

An ordered array based on vapor-processed phthalocyanine nanoribbons
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基于气相处理的酞菁纳米带的有序阵列

DOI:
10.1039/c4tc00123k
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发表时间:
2014-06
影响因子:
6.4
通讯作者:
Liua, Yichun
Liua, Yichun
中科院分区:
材料科学2区
文献类型:
--
作者:
Hu, Wenping;Hu, Wenping;Liua, Yichun;Liua, Yichun

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采用原位气相生长法和基于气相束状纳米带的推动转移法制备了有序排列的CuPc/F16CuPc纳米带。低沉积温度和低蒸汽浓度是小尺寸纳米带生长的关键。在生长过程中,小尺寸纳米带的外部力矩逐渐增大,使得细长的纳米带弯曲并粘附在衬底表面,从而形成原位生长的CuPc/F16CuPc单晶纳米带阵列。另一方面,在高温沉积区常见的束状纳米带的基础上,通过推动转移过程可以形成有序的纳米带阵列。这些结果显示了大规模高效制造有机纳米线/纳米带晶体管的良好潜力。
The ordered arrays of CuPc/F16CuPc nanoribbons have been formed by two different methods, an in situ vapor growth method and a pushing transfer method based on vapor grown bundle-like nanoribbons. Low deposition temperatures and low vapor concentrations are critical for the growth of small-size nanoribbons. During the growth process, the external moment of the small-size nanoribbons gradually increases, which helps to bend and adhere the slim nanoribbons to the substrate surface, thus leading to the formation of in situ grown CuPc/F16CuPc single-crystal nanoribbon arrays. On the other hand, based on the commonly observed bundle-like nanoribbons in a high-temperature deposition region, well ordered nanoribbon arrays can be formed by a pushing transfer process. These results show the promising potential for large-scale and high-efficiency fabrication of organic nanowire/nanoribbon transistors.
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