Influence of Additives on Bath Analysis in Aluminum Electrolysis

Influence of Additives on Bath Analysis in Aluminum Electrolysis
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铝电解中添加剂对镀液分析的影响

DOI:
10.1007/s11837-017-2482-8
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发表时间:
2017-08
期刊:
JOM
影响因子:
2.6
通讯作者:
Xianwei Hu
Xianwei Hu
中科院分区:
材料科学3区
文献类型:
--
作者:
Jianfeng Hou;Dong Shi;Zhaowen Wang;Bingliang Gao;Zhongning Shi;Xianwei Hu

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In this study, the phase compositions of a solid cryolitic electrolyte based on the Na3AlF6-AlF3-KF-LiF-CaF2-Al2O3system have been investigated. Using x-ray diffraction (XRD) and fluoride ion selective electrode analysis (FISEA) techniques, the molar ratio of NaF-AlF3of the cryolitic electrolyte has been determined. The influence of the acidity of the additive electrolytes on the phase compositions of the cryolitic electrolyte has been discussed to gain fundamental insights into understanding the role of additives in such systems. Moreover, an improved XRD-based industrial bath analysis method has been introduced to analyze the composition of the complex cryolitic electrolytes. Finally, based on these results, a new equation has been derived that can be used for FISEA to complement such composition analyses.
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