Cu3Mo2O9 nanosheet incorporated with hemoglobin on carbon ionic liquid electrode for the direct electrochemistry and electrocatalysis
Cu3Mo2O9 nanosheet incorporated with hemoglobin on carbon ionic liquid electrode for the direct electrochemistry and electrocatalysis
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Cu3Mo2O9 纳米片与血红蛋白结合在碳离子液体电极上用于直接电化学和电催化
DOI：
10.1007/s13738-013-0312-7
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发表时间：
2014-04
期刊：
影响因子：
--
通讯作者：
Wei Sun
中科院分区：
文献类型：
--
作者：
Liqi Zhang;Tongtong Li;Ying Deng;Yuanyuan Zhang;Song Hu;Wei Sun
本文采用水热法制备了Cu₃Mo₂O₉纳米片，并以碳离子液体电极（CILE）为基底电极，进一步研究了血红蛋白（Hb）的直接电化学行为。将Hb与Cu₃Mo₂O₉纳米片混合…… （原文最后“Hb was mixed with Cu₃Mo₂O₉ nanosh”表述似乎不完整，推测是nanosheets ，以上按此推测完整翻译）
In this paper Cu3Mo2O9 nanosheet was prepared by a hydrothermal method and further used to investigate the direct electrochemistry of hemoglobin (Hb) with a carbon ionic liquid electrode (CILE) as the substrate electrode. Hb was mixed with Cu3Mo2O9 nanosheet and cast on the CILE surface with chitosan (CTS) as the film-forming material. UV-vis and FT-IR spectroscopic results showed that Hb remained in its native structure in the composite film. Direct electron transfer of Hb on the modified electrode was realized with a pair of well-defined quasi-reversible redox waves that appeared on cyclic voltammograms. The redox peak potential appeared at −0.252 V (Epc) and −0.141 V (Epa), respectively, with the formal peak potential calculated as −0.196 V, which was the characteristic of electroactive center of Hb heme Fe(III)/Fe(II). The result could be attributed to the presence of Cu3Mo2O9 nanosheet on the electrode surface that was of benefit for the protein orientation and promoted direct electron transfer between the redox active center of Hb and the substrate electrode. The CTS/Cu3Mo2O9–Hb/CILE showed good electrocatalytic ability in reducing different substrates such as trichloroacetic acid, H2O2 and O2, with wider linear range and lower detection limit, thus exhibiting the potential application of the Cu3Mo2O9 nanosheet in third-generation electrochemical biosensors.
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影响因子：
6.2
作者：
D. Wei;A. Ivaska
通讯作者：
D. Wei;A. Ivaska
DOI：
10.1002/chin.199834325
发表时间：
1998-05
期刊：
ChemInform
影响因子：
--
作者：
J. Rusling
通讯作者：
J. Rusling
影响因子：
4.6
作者：
S. Vilminot;G. André;M. Richard-Plouet;F. Bourée-Vigneron;M. Kurmoo
通讯作者：
S. Vilminot;G. André;M. Richard-Plouet;F. Bourée-Vigneron;M. Kurmoo
影响因子：
7.4
作者：
Maleki, Norouz;Safavi, Afsaneh;Tajabadi, Fariba
通讯作者：
Tajabadi, Fariba
影响因子：
2
作者：
Wei Sun;Ziqin Zhai;K. Jiao
通讯作者：
Wei Sun;Ziqin Zhai;K. Jiao