Green synthesis of palladium nanoparticles using lentinan for catalytic activity and biological applications.

Green synthesis of palladium nanoparticles using lentinan for catalytic activity and biological applications.
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使用香菇多糖绿色合成钯纳米颗粒,用于催化活性和生物应用

DOI:
10.1039/c9ra08051a
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发表时间:
2019-11-19
期刊:
影响因子:
3.9
通讯作者:
--
中科院分区:
化学3区
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--
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用于催化和生物应用的钯纳米颗粒(Pd NPs)的绿色合成引起了人们的极大兴趣。香菇多糖(LNT)可能是一种很好的还原稳定剂,可以替代复杂的植物提取物。在这项工作中,验证了一种使用LNT还原和稳定Pd纳米粒子的简单、绿色的方法。用紫外-可见光谱、差示扫描量热法、透射电子显微镜和X射线光电子能谱对LNT稳定的钯纳米粒子(PDN-LNT NPs)进行了表征。结果表明,PDN-LNT纳米粒子中的Pd纳米粒子尺寸较小(2.35~3.32 nm)。PDN-LNT纳米粒在溶液中稳定7d。此外,PdN-LNT纳米粒子对4-硝基苯酚的还原具有较高的催化活性。更重要的是,PDN-LNT纳米粒对细胞的毒性可以忽略不计,并显示出良好的抗氧化活性。综上所述,所制备的PDN-LNT纳米粒子在生物相关领域具有巨大的应用潜力。
The green synthesis of palladium nanoparticles (Pd NPs) for catalysis and biological applications has been gaining great interest. To replace complex plant extracts, lentinan (LNT) may be a good reducing and stabilizing agent. In this work, a simple and green method using LNT to reduce and stabilize palladium Pd NPs was verified. The resulting LNT stabilized palladium nanoparticles (Pdn-LNT NPs) were characterized by UV-Vis spectroscopy, DLS, TEM, and XPS. The results indicated that Pd NPs inside of Pdn-LNT NPs had a small size (2.35–3.32 nm). Pdn-LNT NPs were stable in solution for 7 days. In addition, Pdn-LNT NPs had higher catalytic activity towards the reduction of 4-nitrophenol than other catalysts. More importantly, Pdn-LNT NPs had negligible cytotoxicity towards cells and showed good antioxidant activity. Taken together, the prepared Pdn-LNT NPs have great potential bio-related applications.
DOI: 10.1007/s10562-015-1514-7
发表时间: 2015-05-01
期刊: CATALYSIS LETTERS
影响因子: 2.8
作者:
Gu, Sasa;Kaiser, Julian;Wagener, Philipp
通讯作者: Wagener, Philipp
高度生物相容性的枣多糖稳定的钯纳米粒子,具有优异的催化性能
DOI: 10.1039/c9nj00950g
发表时间: 2019-05-28
影响因子: 3.3
作者:
Guo, Xiaolei;Zhang, Jin;Kang, Jianxin
通讯作者: Kang, Jianxin
DOI: 10.1016/j.ijleo.2019.162943
发表时间: 2019-09-01
期刊: OPTIK
影响因子: 3.1
作者:
El-Shabasy, Rehan;Yosri, Nermeen;El-Kemary, Maged
通讯作者: El-Kemary, Maged
DOI: 10.1039/c2gc16359d
发表时间: 2012-01-01
期刊: GREEN CHEMISTRY
影响因子: 9.8
作者:
Li, Haiqing;Han, Lina;Kim, Il
通讯作者: Kim, Il
DOI: 10.1002/aoc.4458
发表时间: 2018-09-01
影响因子: 3.9
作者:
Hamelian, Mona;Zangeneh, Mohammad Mandi;Veisi, Hojat
通讯作者: Veisi, Hojat