Environmentally friendly patterning of molecular waterwheel (Noria) in supercritical carbon dioxide

Environmentally friendly patterning of molecular waterwheel (Noria) in supercritical carbon dioxide
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超临界二氧化碳中分子水车(Noria)的环保图案

DOI:
10.1039/b821475a
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发表时间:
2009
影响因子:
--
通讯作者:
C. Ober
C. Ober
中科院分区:
--
文献类型:
--
作者:
Manabu Tanaka;Abhinav Rastogi;Hiroto Kudo;D. Watanabe;T. Nishikubo;C. Ober

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使用超临界二氧化碳(scCO 2)的环保显影工艺应用于由分子水车(“Noria”)制成的新型分子玻璃抗蚀剂,并通过电子束(EB)光刻进行图案化。Noria衍生物,叔丁氧羰基保护的Noria('Noria-BOC')的物理和光刻性能进行了检查,以评估它作为下一代抗蚀剂的溶解性,成膜能力,热稳定性,光敏性和图案化性能。FT-IR光谱和对比曲线研究分别揭示了Noria-BOC良好的光诱导脱保护反应性和scCO 2显影的优异负性特征。Noria-BOC的EB-图案化,随后在scCO 2中显影,给出了具有亚100 nm分辨率的清晰光刻图案。
An environmentally friendly development process using supercritical carbon dioxide (scCO2) was applied to a novel molecular glass resist made from a molecular waterwheel (‘Noria’), and patterned by electron-beam (EB) lithography. The physical and lithographic properties of a Noria derivative, tert-butoxycarbonyl-protected Noria (‘Noria-BOC’), were examined to evaluate it as a next-generation resist in terms of its solubility, film-forming ability, thermal stability, photosensitivity, and patterning properties. FT-IR spectra and contrast curve studies revealed the good photo-induced deprotection reactivity of Noria-BOC and the excellent negative-tone characteristics of scCO2 development, respectively. The EB-patterning of Noria-BOC followed by development in scCO2 gave clear lithographic patterns with sub-100 nm resolution.
使用超临界二氧化碳对分子玻璃进行高分辨率图案化
DOI: --
发表时间: 2006
期刊: Adv.Mater. 18・4
影响因子: --
作者:
Felix;N.M.;Tsuchiya;K.;Ober;K.C.
通讯作者: K.C.
DOI: 10.1039/b805394d
发表时间: 2008-01-01
影响因子: --
作者:
Kudo, Hiroto;Watanabe, Daisuke;Ober, Christopher K.
通讯作者: Ober, Christopher K.