Ion Mobility Collision Cross Section Compendium.

Ion Mobility Collision Cross Section Compendium.
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DOI:
10.1021/acs.analchem.6b04905
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发表时间:
2017-01-17
影响因子:
7.4
通讯作者:
McLean JA
McLean JA
中科院分区:
化学1区
文献类型:
--
作者:
May JC;Morris CB;McLean JA

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在这篇综述中,我们重点关注离子淌度(IM)研究的一个重要方面,即以气相碰撞截面(CCS)形式报告定量离子淌度测量,这为不同仪器平台之间的比较提供了共同基础,并提供了独特形式的结构信息,即在没有本体溶剂的情况下分析物的尺寸和形状偏好。本综述调查了 1975 年至 2015 年间 IM 方法报告的超过 24,000 个 CCS 值,为迄今为止所做的贡献提供了历史和分析背景,并深入了解了定量离子淌度测量在分析科学中的未来方向。该分析是在 2016 年进行的,因此故意省略了当年报告的 CCS 值。再过几年,对该范围的审查将变得棘手,因为未来三到五年内报告的 CCS 值数量预计将超过目前文献中发表的总量。
In this review, we focus on an important aspect of ion mobility (IM) research, namely the reporting of quantitative ion mobility measurements in the form of the gas-phase collision cross section (CCS), which has provided a common basis for comparison across different instrument platforms and offers a unique form of structural information, namely size and shape preferences of analytes in the absence of bulk solvent. This review surveys the over 24,000 CCS values reported from IM methods spanning the era between 1975 to 2015, which provides both a historical and analytical context for the contributions made thus far, as well as insight into the future directions that quantitative ion mobility measurements will have in the analytical sciences. The analysis was conducted in 2016, so CCS values reported in that year are purposely omitted. In another few years, a review of this scope will be intractable, as the number of CCS values which will be reported in the next three to five years is expected to exceed the total amount currently published in the literature.
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