Multifaceted aspects of charge transfer.
Multifaceted aspects of charge transfer.
复制标题
电荷传输的多方面方面。
DOI：
10.1039/d0cp01556c
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发表时间：
2020-10-14
期刊：
影响因子：
--
通讯作者：
Vullev VI
中科院分区：
文献类型：
--
作者：
Derr JB ;Tamayo J ;Clark JA ;Morales M ;Mayther MF ;Espinoza EM ;Rybicka-Jasińska K ;Vullev VI
电荷转移和电荷传输是迄今为止维持地球上生命和使我们的现代生活方式成为可能的最重要的过程之一。自大氧气事件以来，光合作用和细胞呼吸涉及多个电子转移步骤，主要负责管理我们星球生物圈中的能量流。无法想象没有离子通道介导的电荷传输或氧化还原酶介导的电子和质子转移的生物体。同时，电子和空穴的转移和传输驱动着电子和光子器件的功能，这些功能对我们的生活来说是复杂的。在推动工程进步的同时，电荷转移科学已经成为一个重要的独立领域，起源于物理化学和化学物理，专注于生物学的范式，并从太阳能研究中获得动力。在这里，我们回顾了电荷转移的基本概念，并概述了其在广泛的不相关领域，如医学，环境科学，催化，电子学和光子学的核心作用。例如，偶极子无处不在的性质要求加深对局部电场如何影响电荷转移的理解。电荷转移驻极体，因此，证明是重要的推进领域和接口的基础科学与工程。电荷转移科学截然不同的方面之间的协同作用为该领域的进展所产生的广泛全球影响奠定了基础。
Charge transfer and charge transport are by far among the most important processes for sustaining life on Earth and for making our modern ways of living possible. Involving multiple electron-transfer steps, photosynthesis and cellular respiration have been principally responsible for managing the energy flow in the biosphere of our planet since the Great Oxygen Event. It is impossible to imagine living organisms without charge transport mediated by ion channels, or electron and proton transfer mediated by redox enzymes. Concurrently, transfer and transport of electrons and holes drive the functionalities of electronic and photonic devices that are intricate for our lives. While fueling advances in engineering, charge-transfer science has established itself as an important independent field, originating from physical chemistry and chemical physics, focusing on paradigms from biology, and gaining momentum from solar-energy research. Here, we review the fundamental concepts of charge transfer, and outline its core role in a broad range of unrelated fields, such as medicine, environmental science, catalysis, electronics and photonics. The ubiquitous nature of dipoles, for example, sets demands on deepening the understanding of how localized electric fields affect charge transfer. Charge-transfer electrets, thus, prove important for advancing the field and for interfacing fundamental science with engineering. Synergy between the vastly different aspects of charge-transfer science sets the stage for the broad global impacts that the advances in this field have.
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影响因子：
12.9
作者：
Albero, Josep;Peng, Yong;Garcia, Hermenegildo
通讯作者：
Garcia, Hermenegildo
影响因子：
2.4
作者：
Bahmani, Baharak;Guerrero, Yadir;Anvari, Bahman
通讯作者：
Anvari, Bahman
DOI：
10.1016/s0927-7757(99)00338-6
发表时间：
2000-01-15
影响因子：
5.2
作者：
Appelhans, D;Ferse, D;Adolphi, B
通讯作者：
Adolphi, B
影响因子：
9.5
作者：
Arnoux, Quentin;Boucly, Anthony;Rochet, Francois
通讯作者：
Rochet, Francois
DOI：
10.14219/jada.archive.1973.0186
发表时间：
1973-01-01
影响因子：
3.9
作者：
ALEXANDER, RE
通讯作者：
ALEXANDER, RE