A unique 3D microporous MOF constructed by cross-linking 1D coordination polymer chains for effectively selective separation of CO2/CH4 and C2H2/CH4

A unique 3D microporous MOF constructed by cross-linking 1D coordination polymer chains for effectively selective separation of CO2/CH4 and C2H2/CH4
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由交联一维配位聚合物链构建的独特的3D微孔MOF,可有效选择性分离CO2/CH4和C2H2/CH4

DOI:
10.1016/j.cclet.2020.09.014
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发表时间:
2020-09
影响因子:
9.1
通讯作者:
Bu Xian-He
Bu Xian-He
中科院分区:
化学1区
文献类型:
--
作者:
Xia Yu-Pei;Wang Chen-Xue;Yu Mei-Hui;Bu Xian-He

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Selective separation of CO2/CH4and C2H2/CH4are promising for their high-purity industrial demand and scientific research on account of the similar molecular radius and physical properties. In this work, a unique 3D microporous MOF material [Cu(SiF6)(sdi)2]·solvents (1, sdi = 1,1′-sulfonyldiimidazole) was successfully constructed by cross-linking 1D coordination polymer chains. The dense functional active sites on the inner walls of the channel of1acan provide strong binding affinities to CO2, C2H2, and thus effectively improve the gas separation performance of CO2/CH4and C2H2/CH4.
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