Directed nucleophilic addition of phenoxides to cyclopropenes.

Directed nucleophilic addition of phenoxides to cyclopropenes.
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DOI:
10.1039/c7ob01785e
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发表时间:
2017-10-04
影响因子:
3.2
通讯作者:
Rubin M
Rubin M
中科院分区:
化学3区
文献类型:
--
作者:
Yamanushkin P;Lu-Diaz M;Edwards A;Aksenov NA;Rubina M;Rubin M

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Alkali metal-templated addition of aryloxides across the double bond of non-conjugated cyclopropenes is described. High cis-selectivity is achieved through a directing effect of a strategically-positioned carboxamide functionality. Alkali metal-templated addition of aryloxides across the double bond of non-conjugated cyclopropenes is described. High cis-selectivity is achieved through a directing effect of a strategically-positioned carboxamide functionality.
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