Plasma nitrogenation of polymer surfaces with a new type of combinatorial plasma‐printing reactor
Plasma nitrogenation of polymer surfaces with a new type of combinatorial plasma‐printing reactor
复制标题
使用新型组合等离子体打印反应器对聚合物表面进行等离子体氮化
DOI:
10.1002/ppap.201600137
复制
发表时间:
2016
影响因子:
3.5
通讯作者:
C.-P. Klages
中科院分区:
文献类型:
--
作者:
S. Kotula;M. Lüdemann;J. Philipp;M. Thomas;C.-P. Klages
A new method for combinatorial area‐selective polymer modification or deposition using DBD‐type plasmas at atmospheric pressure (“plasma‐printing”) is presented. Thereby a gradient of two gases perpendicular to the flow direction is established by triangular‐shaped overlapping gas inlets. Design of this reactor allows generation of spot arrays with controlled gradients of physicochemical surface properties which is first applied by investigating the influence of H2admixtures to N2‐plasma‐treatment of polymers. Formation of functional groups is quantitatively characterized by ATR FT‐IR with preceding chemical derivatization using nucleophilic and electrophilic chemicals. It is shown that treatments using high gas flow velocities are more efficient than treatments with low gas speed. Also it is shown that direct plasma treatment leads to polymer surfaces with nucleophilic and electrophilic properties and that H2content influences formation of both types of functionalities.
登录
查看更多内容
DOI:
--
发表时间:
1989
期刊:
影响因子:
--
作者:
T. Hamaya;Y. Kumagai;N. Koshizaki;T. Kanbe
通讯作者:
T. Kanbe
影响因子:
14
作者:
M. Zelzer;R. Majani;J. Bradley;F. Rose;M. Davies;M. Alexander
通讯作者:
M. Zelzer;R. Majani;J. Bradley;F. Rose;M. Davies;M. Alexander
影响因子:
3.6
作者:
Z. Khosravi;C.-P. Klages
通讯作者:
C.-P. Klages
DOI:
--
发表时间:
1960
期刊:
影响因子:
--
作者:
J. Weininger
通讯作者:
J. Weininger
DOI:
--
发表时间:
2013
期刊:
影响因子:
--
作者:
C. Klages;A. Hinze;Z. Khosravi
通讯作者:
Z. Khosravi