Structural optimization and physical properties of TcB3 and MoB3 at high-pressure: First-principles
Structural optimization and physical properties of TcB3 and MoB3 at high-pressure: First-principles
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TcB3和MoB3在高压下的结构优化和物理性质：第一原理
DOI：
10.1142/s0217979216501319
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发表时间：
2016-08
影响因子：
1.7
通讯作者：
Hou Qingyu
中科院分区：
文献类型：
--
作者：
Ying Chun;Bai Xiaowan;Du Yungang;Zhao Erjun;Lin Lin;Hou Qingyu
The thermodynamic, mechanical and dynamic properties of TcB3 and MoB3 are systematically investigated at high-pressure by first-principles within density functional theory (DFT). The calculated formation enthalpies are negative for TcB3 with considered structures under the pressure range from 0 to 100 GPa. Triboride hP4-TcB3 (i.e., TcB3 in hP4-OsB3 type structure) has the lowest formation enthalpy of −1.44 eV under ambient condition. The largest shear modulus of 240 GPa and smallest Poisson’s ratio of 0.20 for oP16-TcB3 are comparable to those of 267 GPa and 0.15 for ReB2. The calculated elastic constants show that MB3 (M=Tc and Mo) are mechanically stable at ambient conditions, except for mP8-MoB3. The estimated high hardness of 33.4 and 33.1 GPa for oP16-TcB3 and hP4-TcB3, respectively, are reported for the first time. The calculated lattice parameters for MoB3 are in good agreement with the previously theoretical and experimental studies. Below 13 GPa, hP16-MoB3 and hR24-MoB3 are thermodynamically more favorable than MoB3 in other structures. A pressure-induced phase transition is predicted at 13 GPa from hP16-MoB3 and hR24-MoB3 to hP4-MoB3. Above 13 GPa, hP4-MoB3 becomes the thermodynamically most stable phase among MoB3 in considered structures. All compounds with considered structures are metallic, and the electronic structures of MB3 are governed by a strong hybridization between M-4d and B-2p states. The strong and directional covalent bonding between M-4d and B-2p as well as the strong interlayer interactions of boron layers are correlated to the high hardness of 38.0 and 38.4 GPa for hP16-MoB3 and hR24-MoB3, respectively.
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合金半导体中位错引起的成分分布
影响因子：
2.1
作者：
Ye, H.;Lu, P. F.;Yu, Z. Y.;Wang, D. L.;Chen, Z. H.;Liu, Y. M.;Wang, S. M.
通讯作者：
Wang, S. M.
根据第一原理，WB3 和 MoB3 的压痕强度出乎意料地低
影响因子：
3.7
作者：
Zang, Chenpeng;Sun, Hong;Chen, Changfeng
通讯作者：
Chen, Changfeng
影响因子：
4
作者：
Yuanxu Wang
通讯作者：
Yuanxu Wang
影响因子：
3.2
作者：
Ravindran, P;Fast, L;Eriksson, O
通讯作者：
Eriksson, O
DOI：
10.1007/bf02881867
发表时间：
1988-08
期刊：
Bulletin of Alloy Phase Diagrams
影响因子：
--
作者：
K. E. Spear;P. Liao
通讯作者：
K. E. Spear;P. Liao