Studies on the structural and electrical properties of F-doped SnO2 film prepared by APCVD

Studies on the structural and electrical properties of F-doped SnO2 film prepared by APCVD
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APCVD制备氟掺杂SnO2薄膜的结构和电学性能研究

DOI:
10.1016/j.apsusc.2011.07.025
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发表时间:
2011-10
影响因子:
6.7
通讯作者:
Zhao, Hongli
Zhao, Hongli
中科院分区:
材料科学1区
文献类型:
--
作者:
Yang, Jingkai;Liu, Wenchang;Dong, Lizhong;Li, Yuanxun;Li, Chuan;Zhao, Hongli

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采用常压化学气相沉积法(APCVD)在Na Ca Si玻璃上沉积了掺氟氧化锡(SnO{sub 2}:F,FTO)薄膜,并在薄膜表面镀上了一层SiO{sub x}C{sub y}扩散阻挡层。700 ℃后热时间的影响。研究了C对SnO{sub 2}:F薄膜结构和电学性能的影响。结果表明,SnO{sub 2}:F薄膜为多晶结构,具有四方SnO {sub 2}结构,薄膜中存在SnO相,并观察到异常晶粒生长。用X射线光电子能谱(XPS)测量了膜层深度的元素分布,发现当加热时间从202 s增加到262 s时,膜层表面的氧含量从78.63%增加到83.38%。电阻率从3.13 × 10{sup-4}增加到4.73 × 10{sup-4} {Ω} cm时,后加热262 s。霍尔迁移率的限制因素是电离杂质散射而不是晶界散射。
Fluorine-doped tin oxide films (SnO{sub 2}:F, FTO) were deposited by atmosphere pressure chemical vapor deposition (APCVD) on Na-Ca-Si glass coated with a diffusion barrier layer of SiO{sub x}C{sub y}. The effects of post-heating time at 700 deg. C on the structural and electrical properties of SnO{sub 2}:F films were investigated. The results showed that SnO{sub 2}:F films were polycrystalline with tetragonal SnO{sub 2} structure, SnO phase was present in SnO{sub 2} film, and abnormal grain growth was observed. The element distribution in the film depth was measured with X-ray photoelectron spectroscopy (XPS) and revealed that when the heating time increased from 202 s to 262 s, the oxygen content in the surface increased from 78.63% to 83.38%. The resistivity increased from 3.13 x 10{sup -4} for as-deposited films to 4.73 x 10{sup -4} {Omega} cm when post-heated for 262 s. Hall mobility is limited by the ionized impurity scattering rather than the grain boundary scattering.
DOI: 10.1016/j.tsf.2008.11.121
发表时间: 2009-03
期刊: Thin Solid Films
影响因子: 2.1
作者:
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发表时间: 2009-03
影响因子: 3.6
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发表时间: 2003-08
影响因子: 2.5
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DOI: 10.1016/j.tsf.2006.01.001
发表时间: 2006-07-03
期刊: THIN SOLID FILMS
影响因子: 2.1
作者:
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通讯作者: Park, Byung-Ok
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发表时间: 1996-06
影响因子: 4.5
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