Effect of ZrO2 morphology on the ablation resistance of carbon/carbon composites containing ZrC prepared by the carbothermal reduction reaction

Effect of ZrO2 morphology on the ablation resistance of carbon/carbon composites containing ZrC prepared by the carbothermal reduction reaction
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ZrO2形貌对碳热还原反应制备含ZrC碳/碳复合材料耐烧蚀性能的影响

DOI:
10.1016/j.corsci.2015.10.033
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发表时间:
2016
期刊:
影响因子:
8.3
通讯作者:
Jianfeng Huang
Jianfeng Huang
中科院分区:
材料科学1区
文献类型:
--
作者:
Cuiyan Li;Kezhi Li;Haibo Ouyang;Jianfeng Huang

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采用ZrO 2与碳的碳热还原反应制备了3种含ZrC颗粒的C/C复合材料(C/C-ZrC)。ZrC分别分布在碳纤维周围、纤维之间和碳基体中,对应于碳纤维预制体中的ZrO 2层、颗粒和晶须。ZrC分散在碳基体中的复合材料具有最好的耐烧蚀性能。ZrC颗粒的弥散分布有利于形成连续熔化的ZrO 2层,防止碳的氧化,抑制复合材料的机械侵蚀。
Three types of carbon/carbon composites containing ZrC particles (C/C-ZrC) were prepared by the carbothermal reduction reaction of ZrO2and carbon. ZrC distributed around the carbon fibers, among the fibers, and dispersed in the carbon matrix corresponding to the ZrO2layer, particles, and whiskers in the carbon fiber preforms, respectively. The composite with ZrC dispersed in the carbon matrix showed the best ablation resistance. Dispersive distribution of the ZrC particles was helpful to form a continuously melting ZrO2layer and this can prevent carbon from oxidizing and restrain the mechanical erosion of the composites.
DOI: 10.1557/jmr.1990.2698
发表时间: 1990-11-01
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