Synthetic Control and Multifunctional Properties of Fluorescent Covalent Triazine-Based Frameworks.
Synthetic Control and Multifunctional Properties of Fluorescent Covalent Triazine-Based Frameworks.
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荧光共价三嗪骨架的合成控制和多功能特性。
DOI：
10.1002/marc.201500615
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发表时间：
2016-02
影响因子：
4.6
通讯作者：
Jiang Jia-Xing
中科院分区：
文献类型：
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作者：
Wang Xiaoyan;Zhang Chong;Zhao Yang;Ren Shijie;Jiang Jia-Xing
共轭微孔聚合物（CMPs）由于具有高孔隙率和光电活性的优点，吸引了越来越多的研究兴趣，并已应用于各种环境和能源领域。高效合成以及新型（材料）的开发……
Conjugated microporous polymers (CMPs), with the virtue of high porosity and optoelectronic activity, are attracting increasing research interest and have been used in various environmental and energy areas. Efficient synthesis and the exploitation of new functionalities are the research hotspots in the CMPs research area. Covalent triazine frameworks (CTFs) synthesized by CF3 SO3 H catalyzed trimerization reactions show properties quite alike to CMPs and this method avoids the use of noble metal catalysts. In this study, a series of novel fluorescent covalent triazine-based frameworks (F-CTFs) is prepared using different tetra-cyano compounds as the starting monomers. Both porosity and fluorescence properties of the F-CTFs can be adjusted by the monomer structure. Gas adsorption measurement reveals that F-CTF1 with the largest surface area of 896 m(2) g(-1) shows the highest CO2 uptake of 3.29 mmol g(-1) at 273 K and 1.13 bar among the polymers. Taking advantages of their large surface areas and strong fluorescence, these F-CTFs could be used as efficient chemical sensing agents for various nitroaromatic compounds as well.
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影响因子：
8.6
作者：
Rabbani, Mohammad Gulam;El-Kaderi, Hani M.
通讯作者：
El-Kaderi, Hani M.
基于咔唑氧化偶联聚合的含氮微孔共轭聚合物：制备、孔隙率和气体吸收
影响因子：
13.3
作者：
Chen, Qi;Liu, De-Peng;Han, Bao-Hang
通讯作者：
Han, Bao-Hang
影响因子：
--
作者：
Wang Zhang;Cun Li;Yupeng Yuan;L. Qiu;A. Xie;Yuhua Shen;Junfa Zhu
通讯作者：
Wang Zhang;Cun Li;Yupeng Yuan;L. Qiu;A. Xie;Yuhua Shen;Junfa Zhu
影响因子：
16.6
作者：
Cheng, Ge;Hasell, Tom;Cooper, Andrew I.
通讯作者：
Cooper, Andrew I.
影响因子：
15
作者：
Liu, Xiaoming;Xu, Yanhong;Jiang, Donglin
通讯作者：
Jiang, Donglin