Femtosecond Laser Deposition of Germanium Selenide onto Silicon Platform at Different Substrate Temperatures.

Femtosecond Laser Deposition of Germanium Selenide onto Silicon Platform at Different Substrate Temperatures.
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飞秒激光沉积硒化汁在不同的底物温度下在硅平台上。

DOI:
10.3390/nano12122003
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发表时间:
2022-06-10
期刊:
Nanomaterials (Basel, Switzerland)
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采用飞秒脉冲激光沉积(fs-PLD)技术,在25 °C ~ 600 °C的不同衬底温度下,在硅(100)衬底上制备了硒化锗(GeSe)薄膜。利用透射电子显微镜(TEM)和X射线衍射(XRD)研究了薄膜的表面形貌和光学性能。X射线衍射结果表明,在低于400 °C的衬底温度下沉积在硅上的薄膜是非晶Ge-Se。相比之下,在400 °C及以上生长的样品显示出Ge-Se正交和四方结构的结晶峰。薄膜的沉积生长速率也被发现随衬底温度的升高而显著降低。这些结果表明,fs-PLD工艺在制备高质量Ge-Se薄膜方面具有很大的潜力。这种技术可以使现代光电子器件的制造应用在光通信,传感和双向阈值开关的高密度交叉存储器阵列。
Germanium selenide (GeSe) thin films were fabricated by employing femtosecond pulsed-laser deposition (fs-PLD) on silicon (100) substrates at various substrate temperatures, ranging from 25 °C to 600 °C. The thin films’ surface morphology qualities and optical properties were studied by utilising transmission electron microscopy (TEM) and X-ray diffraction (XRD). The X-ray diffraction result signifies that the thin films deposited on the silicon at a substrate temperature below 400 °C were amorphous Ge-Se. In contrast, those grown at 400 °C and above exhibited crystallised peaks of Ge-Se orthorhombic and tetragonal structures. The deposition growth rate of the thin films was also found to decrease substantially with increasing substrate temperature. These results show that the fs-PLD process has great potential for fabricating good quality Ge-Se thin film. This technique could enable the manufacture of modern optoelectronic devices for applications in optical communication, sensing, and ovonic threshold switching for the high-density crossbar memory array.
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