Titin-mimicking polycyclic polymers with shape regeneration and healing properties

Titin-mimicking polycyclic polymers with shape regeneration and healing properties
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具有形状再生和愈合特性的仿钛多环聚合物

DOI:
10.1039/c4py01458h
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发表时间:
2015
期刊:
影响因子:
4.6
通讯作者:
P. Vana
P. Vana
中科院分区:
化学2区
文献类型:
--
作者:
J.-H. Schuetz;W. Peng;P. Vana

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基于环状(ABC)n-多嵌段共聚物的多环聚合物通过三个单独嵌段的逐步聚合并利用这些环聚合物的环合并反应形成。如此获得的前体环聚合物通过点击反应互连。具有形成自互补氢键能力的环内的小嵌段导致多环聚合物之间的分子内和分子间连接。所获得的材料,模仿自然界的典范Titin,具有一些非凡的材料特性,涉及弹性和能量耗散。
Polycyclic polymers based on cyclic (ABC)n-multiblock-copolymers are formed via stepwise polymerization of three individual blocks and exploiting the ring merging reaction of these ring polymers. The so-obtained precursor ring-polymers were interconnected via click reaction. Small blocks within the rings with the ability to form self-complementary hydrogen bonds lead to intra- and intermolecular links between polycyclic polymers. The obtained materials, which mimic nature's paragon Titin, have some extraordinary material properties concerning elasticity and energy dissipation.
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