Stimuli Responsive Polymer-Based 3D Optical Crystals for Sensing

Stimuli Responsive Polymer-Based 3D Optical Crystals for Sensing
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用于传感的刺激响应聚合物基 3D 光学晶体

DOI:
10.3390/polym911043
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发表时间:
2017-10
期刊:
影响因子:
5
通讯作者:
Samuel M. Mugo
Samuel M. Mugo
中科院分区:
工程技术3区
文献类型:
--
作者:
Qiang Zhang;Michael J. Serpe;Samuel M. Mugo

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3D光学晶体已在传感、驱动、光学器件、电池、超级电容器等领域得到应用。3D光学晶体器件由两个主要成分组成:胶体凝胶和纳米颗粒。纳米颗粒在胶体凝胶中自组装成面心立方结构。固有的 3D 光学晶体结构可在光照射后在这些设备上显示结构颜色。因此,这些光学特性使得这些 3D 光学晶体被用作自报告比色传感器,这是本文的重点。虽然到目前为止,在这些材料上已经做了大量的工作,本次综述将对其进行详尽的介绍,但我们在此重点关注:彩色显示机制、3D光学晶体的材料和制备、最新传感实例的介绍以及3D光学晶体与分子印迹技术的结合。本综述的目的是让读者熟悉该领域的最新发展,并鼓励该领域的进一步研究,以克服其一些挑战,并激发这些材料的创造性创新。
3D optical crystals have found their applications in sensing, actuation, optical devices, batteries, supercapacitors, etc. The 3D optical crystal devices are comprised of two main components: colloidal gels and nanoparticles. Nanoparticles self-assemble into face center cubic structures in colloidal gels. The inherent 3D optical crystal structure leads to display of structural colors on these devices following light impingement. As such, these optical properties have led to the utilization of these 3D optical crystals as self-reporting colorimetric sensors, which is the focus of this review paper. While there is extensive work done so far on these materials to exhaustively be covered in this review, we focus here in on: mechanism of color display, materials and preparation of 3D optical crystals, introduction of recent sensing examples, and combination of 3D optical crystals with molecular imprinting technology. The aim of this review is to familiarize the reader with recent developments in the area and to encourage further research in this field to overcome some of its challenges as well as to inspire creative innovations of these materials.
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