Flexible white phosphorescent organic light emitting diodes based on multilayered graphene/PEDOT:PSS transparent conducting film

Flexible white phosphorescent organic light emitting diodes based on multilayered graphene/PEDOT:PSS transparent conducting film
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基于多层石墨烯/PEDOT:PSS透明导电薄膜的柔性白色磷光有机发光二极管

DOI:
10.1016/j.apsusc.2014.01.034
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发表时间:
2014-03
影响因子:
6.7
通讯作者:
Guo Tailiang
Guo Tailiang
中科院分区:
材料科学1区
文献类型:
--
作者:
Wu Xiaoxiao;Li Fushan;Wu Wei;Guo Tailiang

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制备了一种双层石墨烯/聚(3,4-乙烯二氧噻吩):聚苯乙烯磺酸盐(PEDOT:PSS)导电薄膜,其中PEDOT:PSS层采用喷涂技术制备。制备了一种基于石墨烯/PEDOT:PSS导电膜的柔性白光有机发光器件。将荧光材料三(2-苯基吡啶)铱(Ir(ppy)3)与荧光染料5,6,11,12-四苯基萘(Rubrene)共掺杂到4,4 ' -N,N ' -二咔唑-联苯(CBP)中。以N,N ' -二苯基-N,N ' -双(1-萘基)-(1,1 ' -联苯基)-4,4 ' -二胺(NPB)和4,7-二苯基-1,10-菲罗啉(Bphen)分别作为空穴传递层和电子传递层,以4,4 ' -双(2,2 ' -二苯基乙烯基)-1,1 ' -联苯(DPVBi)作为蓝光发光层。该器件呈现出纯白光发射,国际委员会De I 'Eclairage坐标为(0.31,0.33),并且在曲率半径为10 mm的弯曲循环测试中表现出优异的发光稳定性。
A double-layered graphene/poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) conductive film was prepared, in which the PEDOT:PSS layer was obtained by using spray-coating technique. A flexible white phosphorescent organic light-emitting devices based on the graphene/PEDOT:PSS conductive film was fabricated. Phosphorescent material tris(2-phenylpyridine) iridium (Ir(ppy)3) and the fluorescent dye 5,6,11,12-tetraphenylnapthacene (Rubrene) were co-doped into 4,4′-N,N′-dicarbazole-biphenyl (CBP) host. N,N′-diphenyl-N,N′-bis(1-naphthyl)-(1,1′-biphenyl)-4,4′-diamine (NPB) and 4,7-diphenyl-1,10-phenanthroline (Bphen) were used as hole-transporting and electron-transporting layer, respectively, and 4,4′-bis(2,2′-diphenylvinyl)-1,1′-biphenyl (DPVBi) was used as blue light-emitting layer. The device presented pure white light emission with a Commission Internationale De I’Eclairage coordinates of (0.31, 0.33) and exhibited an excellent light-emitting stability during the bending cycle test with a radius of curvature of 10 mm.
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