Nanoscale polyoxometalate-based inorganic/organic hybrids.

Nanoscale polyoxometalate-based inorganic/organic hybrids.
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纳米级多金属氧酸盐基无机/有机杂化物。

DOI:
10.1002/tcr.201100002
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发表时间:
2011-06
期刊:
影响因子:
6.6
通讯作者:
--
中科院分区:
化学2区
文献类型:
--
作者:

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The latest advances in the area of polyoxometalate (POM)-based inorganic/organic hybrid materials prepared by self-assembly, covalent modification, and supramolecular interactions are presented. This Review is composed of five sections and documents the effect of organic cations on the formation of novel POMs, surfactant encapsulated POM-based hybrids, polymeric POM/organic hybrid materials, POMs-containing ionic crystals, and covalently functionalized POMs. In addition to their role in the charge-balancing, of anionic POMs, the crucial role of organic cations in the formation and functionalization of POM-based hybrid materials is discussed.
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