The Development of Visible-Light Photoredox Catalysis in Flow.
The Development of Visible-Light Photoredox Catalysis in Flow.
复制标题
DOI：
10.1002/ijch.201300136
复制
发表时间：
2014-04-01
影响因子：
3.2
通讯作者：
Stephenson, Corey R. J.
中科院分区：
文献类型：
--
作者：
Garlets, Zachary J.;Nguyen, John D.;Stephenson, Corey R. J.
可见光光氧化还原催化最近已成为一个可行的替代自由基反应，否则进行锡和硼试剂。已经认识到，通过将光氧化还原催化与流动化学合并，可以避免反应时间慢、产率低和安全问题。虽然流动反应器已成功地应用于用UV光进行的反应，但只有最近的发展才证明流动反应器在改善可见光介导的反应方面具有相同的潜力。这篇综述探讨了可见光介导的光氧化还原流动化学的初始和持续发展，举例说明流动化学的好处相比，传统的批处理技术。
Visible-light photoredox catalysis has recently emerged as a viable alternative for radical reactions otherwise carried out with tin and boron reagents. It has been recognized that by merging photoredox catalysis with flow chemistry, slow reaction times, lower yields, and safety concerns may be obviated. While flow reactors have been successfully applied to reactions carried out with UV light, only recent developments have demonstrated the same potential of flow reactors for the improvement of visible-light-mediated reactions. This review examines the initial and continuing development of visible-light-mediated photoredox flow chemistry by exemplifying the benefits of flow chemistry compared with conventional batch techniques.
登录
查看更多内容
DOI：
10.1039/c39790000978
发表时间：
1979-01-01
影响因子：
--
作者：
GAREGG, PJ;SAMUELSSON, B
通讯作者：
SAMUELSSON, B
影响因子：
12.9
作者：
Rueping, Magnus;Vila, Carlos;Bootwicha, Teerawut
通讯作者：
Bootwicha, Teerawut
影响因子：
15
作者：
Nguyen, John D.;Tucker, Joseph W.;Konieczynska, Marlena D.;Stephenson, Corey R. J.
通讯作者：
Stephenson, Corey R. J.
影响因子：
16.6
作者：
Neumann, Matthias;Fueldner, Stefan;Zeitler, Kirsten
通讯作者：
Zeitler, Kirsten
影响因子：
5.2
作者：
Hernandez-Perez, Augusto C.;Vlassova, Anna;Collins, Shawn K.
通讯作者：
Collins, Shawn K.