Recent advances in homogeneous nickel catalysis.

Recent advances in homogeneous nickel catalysis.
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DOI:
10.1038/nature13274
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发表时间:
2014-05-15
期刊:
影响因子:
64.8
通讯作者:
Jamison TF
Jamison TF
中科院分区:
综合性期刊1区
文献类型:
--
作者:
Tasker SZ;Standley EA;Jamison TF

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镍催化领域在过去的十年中取得了巨大的进步。镍的几个关键特性允许广泛的创新反应开发,例如容易的氧化加成和容易获得多种氧化态。近年来,这些属性已被越来越多地理解和利用来执行长期以来被认为极具挑战性的转换。在此,我们讨论了一些最新的和显着的发展,均相镍催化剂的合成结果和机制的重点。
The field of nickel catalysis has made tremendous advances in the past decade. There are several key properties of nickel that have allowed for a broad range of innovative reaction development, such as facile oxidative addition and ready access to multiple oxidation states. In recent years, these properties have been increasingly understood and leveraged to perform transformations long considered exceptionally challenging. Herein, we discuss some of the most recent and significant developments in homogeneous nickel catalysis with an emphasis on both synthetic outcome and mechanism.
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