Iridium-catalysed dehydrocoupling of aryl phosphine-borane adducts: synthesis and characterisation of high molecular weight poly(phosphinoboranes).
Iridium-catalysed dehydrocoupling of aryl phosphine-borane adducts: synthesis and characterisation of high molecular weight poly(phosphinoboranes).
复制标题
铱催化芳基膦-硼烷加合物的脱氢偶联:高分子量聚(膦基硼烷)的合成和表征。
DOI:
10.1039/c6cc04363a
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发表时间:
2016
影响因子:
4.9
通讯作者:
U. Radius
中科院分区:
文献类型:
--
作者:
Ursula S. D. Paul;H. Braunschweig;U. Radius
The thermal dehydrogenative coupling of aryl phosphine-borane adducts with iridium complexes bearing a bis(phosphinite) pincer ligand is reported. This catalysis produces high molecular weight poly(phosphinoboranes) [ArPH-BH2]n (Ar = Ph, (p)Tol, Mes). Furthermore, we investigated the reactivity of these pincer complexes towards primary phosphines and their respective borane adducts on a stoichiometric scale.
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DOI:
10.1002/anie.201507084
发表时间:
2015-11-09
期刊:
Angewandte Chemie (International ed. in English)
影响因子:
--
作者:
Marquardt C;Jurca T;Schwan KC;Stauber A;Virovets AV;Whittell GR;Manners I;Scheer M
通讯作者:
Scheer M
影响因子:
15
作者:
Göttker-Schnetmann, I;White, P;Brookhart, M
通讯作者:
Brookhart, M
影响因子:
4.3
作者:
Marquardt, Christian;Adolf, Ariane;Scheer, Manfred
通讯作者:
Scheer, Manfred
影响因子:
15
作者:
Vance, James R.;Schaefer, Andre;Manners, Ian
通讯作者:
Manners, Ian
影响因子:
16.6
作者:
Staubitz, Anne;Soto, Alejandro Presa;Manners, Ian
通讯作者:
Manners, Ian