Fluorine-Driven Enhancement of Birefringence in the Fluorooxosulfate: A Deep Evaluation from a Joint Experimental and Computational Study.
Fluorine-Driven Enhancement of Birefringence in the Fluorooxosulfate: A Deep Evaluation from a Joint Experimental and Computational Study.
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DOI：
10.1002/advs.202003594
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发表时间：
2021-08
期刊：
影响因子：
--
通讯作者：
Pan S
中科院分区：
文献类型：
--
作者：
Jin W;Zhang W;Tudi A;Wang L;Zhou X;Yang Z;Pan S
Understanding and exploring the functional modules (FMs) consisting of local atomic groups can promote the development of the materials with functional performances. Oxygen‐containing tetrahedral modules are popular in deep‐ultraviolet (DUV) optical materials, but their weak optical anisotropy is adverse to birefringence. Here, the fluorooxosulfate group is proved as a new birefringence‐enhanced FM for the first time. The birefringence of fluorooxosulfates can be 4.8–15.5 times that of sulfates with the same metal cations while maintaining a DUV band gap. The polarizing microscope measurement confirms the birefringence enhancement by using the millimeter crystals experimentally. The theoretical studies from micro and macro levels further reveal a novel universal strategy that the fluorine induced anisotropic electronic distribution in fluorooxo–tetrahedral group is responsible for the enhancement of birefringence. This study will guide the future discovery of DUV optical materials with enlarged birefringence. A novel design and synthesis strategy for birefringent materials. The fluorooxosulfate group is proved as a new birefringence‐enhanced FM for the first time. The fluorine‐free tetrahedra substituted by the fluorooxo‐tetrahedral group can enhance birefringence while maintaining short cut‐off edge, which is proved by the experiments. This study provides a feasible way to design DUV optical materials with enlarged birefringence.
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