Stoichiometric control of multiple different tectons in coordination-driven self-assembly: preparation of fused metallacyclic polygons.

Stoichiometric control of multiple different tectons in coordination-driven self-assembly: preparation of fused metallacyclic polygons.
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DOI:
10.1021/ja903330j
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发表时间:
2009-09-02
影响因子:
15
通讯作者:
Stang, Peter J.
Stang, Peter J.
中科院分区:
化学1区
文献类型:
--
作者:
Lee, Junseong;Ghosh, Koushik;Stang, Peter J.

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我们提出了一种合成稳定的多组分稠合多边形配合物的一般策略,其中配位驱动自组装允许单一超分子物种由多组分自组装而成,所获得的多边形的形状可以通过简单地改变单个组分的比例来控制。化合物的结构经多核核磁共振、电喷雾质谱确证。
We present a general strategy for the synthesis of stable, multi-component fused polygon complexes where coordination-driven self-assembly allows for single supramolecular species can be formed from multi-component self-assembly and the shape of the obtained polygons can be controlled by simply changing the ratio of individual components. The compounds are characterized by Multinuclear NMR, ESI Mass spectrometry.
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