Controlled/living radical polymerization in environmentally friendly miniemulsions induced by compressed carbon dioxide for synthesis of nanoparticles and well-defined polymer

由压缩二氧化碳诱导的环保细乳液中的受控/活性自由基聚合用于合成纳米粒子和明确的聚合物

• 批准号: DP1093343
• 负责人: Prof Per Setterlund
• 金额: $ 20.8万
• 依托单位: The University of New South Wales
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2010
• 资助国家: 澳大利亚
• 起止时间: 2010-01-05 至 2013-01-04
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP1093343
• 关键词: Controlled; living; radical; polymerization; environmentally

Controlled/living radical polymerization is a technique for precise synthesis of polymer by radical polymerization, which has revolutionized polymer synthesis in terms of accessible polymer structures. However, controlled/living radical polymerization has yet to gain a strong foothold in industry mainly due to problems associated with its implementation in (aqueous) dispersed systems. The present Proposal addresses this key challenge by a novel environmentally friendly and versatile method for aqueous miniemulsion preparation by use of compressed carbon dioxide. Controlled/living radical polymerization in dispersed systems generates polymeric nanoparticles, which are of importance in many advanced and emerging technologies.

受控/生命的自由基聚合是一种通过自由基聚合物来精确合成聚合物的技术，从根部聚合物化中，它已经用可访问的聚合物结构彻底改变了聚合物的合成。但是，受控/生活的激进聚合尚未在行业中获得强大的立足点，这主要是由于其在（水性）分散系统中实施相关的问题。本提案通过一种通过使用压缩二氧化碳的新型环境友好和多功能的方法来解决这一主要挑战。分散系统中的受控/生命自由基聚合产生聚合物纳米颗粒，这些纳米颗粒在许多高级和新兴技术中都很重要。