Biomimetic templating radical polymerisation in nanoreactors

纳米反应器中的仿生模板自由基聚合

• 批准号: DP140100292
• 负责人: Prof Per Setterlund
• 金额: $ 25.17万
• 依托单位: The University of New South Wales
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2014
• 资助国家: 澳大利亚
• 起止时间: 2014-01-01 至 2017-12-31
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP140100292
• 关键词: Biomimetic; templating; radical; polymerisation; nanoreactors

The aim is to develop methodology for synthesis of polymer with hitherto inaccessible control of the microstructure by free radical means, that is the molecular weight distribution and monomer sequences. This will be achieved by combining the two concepts of biomimetic templated radical polymerisation and polymerisation in nanoreactors in the form of submicron-sized micelles or droplets. Scale-up of the methodology will be developed based on an environmentally friendly approach whereby miniemulsions are generated using carbon dioxide. Increased ability to control the polymer microstructure will enable advanced design of functional polymers with far-reaching applications in materials science, nanotechnology and nanomedicine.

其目的是开发合成聚合物的方法学，到目前为止还无法通过自由基手段控制聚合物的微观结构，即分子量分布和单体序列。这将通过结合仿生模板化自由基聚合和在纳米反应器中以亚微米尺寸胶束或液滴的形式聚合这两个概念来实现。该方法的扩大将基于一种环境友好的办法，即利用二氧化碳产生微型乳状液。提高控制聚合物微结构的能力将使先进的功能聚合物设计成为可能，在材料科学、纳米技术和纳米医学中具有深远的应用。