Kinetics of Gas-Phase Reactions of Metallic Species Over Wide Temperature Ranges

研究正在进行中，以扩大金属的温度范围， 化学是可以理解的。 还需要研究的是 包括金属氧化物和一卤化物。 这个较高的范围（最多 1900K）需要设计一个准静态光化学反应器 (HTP)反应可以在没有墙的情况下启动和监测， 干扰 在这些实验条件下， 限制消失，前者，很好地理解，快速流动技术 （HTFFR）可以另外使用，这两个交叉验证 方法成为可能。 加上准分子激光器 可能的光解产生广泛的金属， 他们的化合物。 所考虑的反应涉及Mn、Ba、Cu、Al和Mn。 约 飞灰和烟尘中这些元素的存在是导致 腐蚀结垢甚至粉尘爆炸的问题。 相反地， 一些工业过程（例如炭黑生成、化学气相 电子制造中的沉积）取决于此类化学物质 活动 这些新知识对工业实践的影响 可能会很重要

Research is underway to extend the range of temperatures in which metal chemistry is understood. Also to be studied are the reactions involving metallic oxides and monohalides. This higher range (up to 1900K) requires the design of a pseudo static photochemistry reactor (HTP) where reactions can be initiated and monitored without wall interference. In these experimental conditions where the wall limitations disappear, the former, well understood, fast flow technique (HTFFR) can be used in addition, and the cross validation of these two methods become possible. The addition of an excimer laser would make possible the photolytic generation of a broad range of metals from their compounds. The reactions contemplated involve Mn, Ba, Cu, Al and Ca. The presence of these elements in fly ash and soot is the cause of problems of corrosion fouling or even dust explosions. Conversely, some industrial processes (e.g. carbon black generation, chemical vapor deposition in electronics manufactures) depend on such chemical activities. The impact on such new knowledge on industrial practice could be substantial.