Purchase of an ESR Spectrometer (Chemistry)

购买ESR光谱仪（化学）

• 批准号: 8715933
• 负责人: Bernard Kirtman
• 金额: --
• 依托单位: University of California-Santa Barbara
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1988
• 资助国家: 美国
• 起止时间: 1988-07-01 至 1990-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=8715933&HistoricalAwards=false
• 关键词: Purchase; ESR; Spectrometer; Chemistry

Electron Spin Resonance (ESR) spectroscopy is a technique used by chemists to study the properties of molecules having an electronic configuration containing unpaired electrons. In this manner, the structures of a wide variety of intermediates can be understood. The Department of Chemistry at the University of California, Santa Barbara will use this award that is joint-funded by the Chemistry Shared Instrumentation Program, the Biology Instrumentation Program, and the Instrumentation for Materials Research Program to help acquire an ESR spectrometer. Some of the areas of research that will be enhanced by the acquisition include: 1) Mechanisms of biochemically important oxidation-reduction reactions 2) Metallo-protein studies 3) Design, synthesis, and characterization of new microporous hosts 4) Characterization of ferromagnetic metal molecular intermediates 5) Nucleophilic aromatic substitution 6) Photoreactions of metal complexes 7) Studies related to the 1,3-diyl trapping reaction.

电子自旋共振(ESR)谱是化学家用来研究含有未成对电子的电子构型的分子的性质的一种技术。通过这种方式，可以理解各种中间体的结构。加州大学圣巴巴拉分校化学系将利用这一由化学共享仪器计划、生物仪器计划和材料研究仪器计划联合资助的奖项，帮助获得ESR光谱仪。收购将加强的一些研究领域包括：1)具有生物化学意义的氧化还原反应的机理2)金属蛋白质研究3)新的微孔宿主的设计、合成和表征4)铁磁性金属分子中间体的表征5)亲核芳香族取代6)金属络合物的光反应7)与1，3-二基捕获反应相关的研究。