Experimental and Theoretical Investigations of Organic Reaction Rates and Mechanisms

有机反应速率和机理的实验和理论研究

• 批准号: 8810457
• 负责人: Robert Armstrong
• 金额: $ 42.06万
• 依托单位: University of California-Los Angeles
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1989
• 资助国家: 美国
• 起止时间: 1989-01-15 至 1991-12-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=8810457&HistoricalAwards=false
• 关键词: Experimental; Theoretical; Investigations; Organic; Reaction

This project is a continuation of experimental and theoretical studies of reactions of organic molecules in order to determine the timing of bond formation in these systems and to develop a general theory of reactivity in pericyclic reactions based upon transition-state molecular orbitals. The relationship of ground-state distortions to stereoselectivity will be probed by calculations and x-ray structure determinations.

这个项目是实验和理论的延续 研究有机分子的反应，以确定 这些系统中键形成的时间，并制定一个 周环反应的一般反应性理论， 过渡态分子轨道 的关系 立体选择性的基态扭曲将被探测， 计算和X射线结构测定。