Reactions and Stereochemistry of Organometallic Compounds Related to Asymmetric Synthesis and Catalytic Activity
与不对称合成和催化活性相关的有机金属化合物的反应和立体化学
基本信息
- 批准号:9004333
- 负责人:
- 金额:$ 34.66万
- 依托单位:
- 依托单位国家:美国
- 项目类别:Continuing Grant
- 财政年份:1990
- 资助国家:美国
- 起止时间:1990-05-15 至 1994-04-30
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
The goal of this project in the Inorganic, Bioinorganic and Organometallic Chemistry Program is the development of new methods for stereoselective synthesis of organic compounds based on compounds containing such transition metals as tungsten and molybdenum. Such methods are extremely important because the three-dimensional structure of a molecule can affect profoundly its chemical and biological properties. The two aims of the project are the development of new methods using metal complexes for asymmetric and regioselective syntheses and the elucidation of the mechanisms of stereoselective reactions which are synthetically useful. The potential utility of higher oxidation state organometallic complexes for these applications will be explored also. A new method will be developed for obtaining detailed structural information for organometallic compounds in solution. Ligands containing paramagnetic metal ions which bind to organometallics will be designed and synthesized. NMR measurements using these new shift reagents will allow detailed delineation of structure (angles and distances) of reactive organometallic species, especially catalytic intermediates, which exist only in solution.
无机、生物无机和有机金属化学项目的该项目的目标是开发基于含有钨和钼等过渡金属的化合物的有机化合物立体选择性合成的新方法。这些方法极其重要,因为分子的三维结构可以深刻地影响其化学和生物特性。 该项目的两个目标是开发使用金属配合物进行不对称和区域选择性合成的新方法,以及阐明合成上有用的立体选择性反应的机制。还将探讨较高氧化态有机金属配合物在这些应用中的潜在效用。将开发一种新方法来获取溶液中有机金属化合物的详细结构信息。将设计和合成含有与有机金属结合的顺磁性金属离子的配体。使用这些新的位移试剂进行核磁共振测量将可以详细描述活性有机金属物质的结构(角度和距离),特别是仅存在于溶液中的催化中间体。
项目成果
期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
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John Faller其他文献
John Faller的其他文献
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{{ truncateString('John Faller', 18)}}的其他基金
Reactions and Stereochemistry of Organometallic Compounds Related to Asymmetric Synthesis and Catalytic Activity
与不对称合成和催化活性相关的有机金属化合物的反应和立体化学
- 批准号:
0092222 - 财政年份:2001
- 资助金额:
$ 34.66万 - 项目类别:
Continuing Grant
Reactions and Stereochemistry of Organometallic Compounds Related to Asymmetric Synthesis and Catalytic Activity
与不对称合成和催化活性相关的有机金属化合物的反应和立体化学
- 批准号:
9726423 - 财政年份:1998
- 资助金额:
$ 34.66万 - 项目类别:
Continuing Grant
Reactions and Sterochemistry of Organometallic Compounds Related to Asymmetric Synthesis and Catalytic Activity
与不对称合成和催化活性相关的有机金属化合物的反应和立体化学
- 批准号:
9320668 - 财政年份:1994
- 资助金额:
$ 34.66万 - 项目类别:
Continuing Grant
U.S.-France Cooperative Research: Asymmetric Catalysis With Chiral Metal Centers
美法合作研究:手性金属中心不对称催化
- 批准号:
9115700 - 财政年份:1992
- 资助金额:
$ 34.66万 - 项目类别:
Standard Grant
Reactions and Stereochemistry of Organometallic Compounds Related to Asymmetric Synthesis and Catalytic Activity
与不对称合成和催化活性相关的有机金属化合物的反应和立体化学
- 批准号:
8708595 - 财政年份:1987
- 资助金额:
$ 34.66万 - 项目类别:
Continuing Grant
Reactions and Stereochemistry of Organometallic Compounds Related to Asymmetric Synthesis and Catalytic Activity (Chemistry)
与不对称合成和催化活性相关的有机金属化合物的反应和立体化学(化学)
- 批准号:
8404516 - 财政年份:1984
- 资助金额:
$ 34.66万 - 项目类别:
Continuing Grant
Reactions and Stereochemistry of Organometallic Compounds Related to Asymmetric Synthesis and Catalytic Activity
与不对称合成和催化活性相关的有机金属化合物的反应和立体化学
- 批准号:
8208042 - 财政年份:1982
- 资助金额:
$ 34.66万 - 项目类别:
Continuing Grant
Reactions and Stereochemistry of Organometallic Compounds Related to Asymmetric Syntheses and Catalytic Activity
与不对称合成和催化活性相关的有机金属化合物的反应和立体化学
- 批准号:
7911201 - 财政年份:1979
- 资助金额:
$ 34.66万 - 项目类别:
Continuing Grant
Reactions and Stereochemistry of Organometallic Compounds Related to Asymmetric Syntheses and Catalytic Activity
与不对称合成和催化活性相关的有机金属化合物的反应和立体化学
- 批准号:
7714943 - 财政年份:1977
- 资助金额:
$ 34.66万 - 项目类别:
Continuing Grant
Travel to Attend: Eighth International Conference on Organometallic Chemistry, Kyoto, Japan, 09/12-16/77
前往参加:第八届国际有机金属化学会议,日本京都,09/12-16/77
- 批准号:
7711572 - 财政年份:1977
- 资助金额:
$ 34.66万 - 项目类别:
Standard Grant
相似海外基金
Reactions and Stereochemistry of Organometallic Compounds Related to Asymmetric Synthesis and Catalytic Activity
与不对称合成和催化活性相关的有机金属化合物的反应和立体化学
- 批准号:
0092222 - 财政年份:2001
- 资助金额:
$ 34.66万 - 项目类别:
Continuing Grant
Reactions and Stereochemistry of Organometallic Compounds Related to Asymmetric Synthesis and Catalytic Activity
与不对称合成和催化活性相关的有机金属化合物的反应和立体化学
- 批准号:
9726423 - 财政年份:1998
- 资助金额:
$ 34.66万 - 项目类别:
Continuing Grant
Reactions and Stereochemistry of Organometallic Compounds Related to Asymmetric Synthesis and Catalytic Activity
与不对称合成和催化活性相关的有机金属化合物的反应和立体化学
- 批准号:
8708595 - 财政年份:1987
- 资助金额:
$ 34.66万 - 项目类别:
Continuing Grant
Reactions and Stereochemistry of Organometallic Compounds Related to Asymmetric Synthesis and Catalytic Activity (Chemistry)
与不对称合成和催化活性相关的有机金属化合物的反应和立体化学(化学)
- 批准号:
8404516 - 财政年份:1984
- 资助金额:
$ 34.66万 - 项目类别:
Continuing Grant
Stereochemistry and Mechanisms of Organometallic Insertion and Rearrangement Reactions With Unsaturated Hydrocarbons (Chemistry)
不饱和烃金属有机插入和重排反应的立体化学和机制(化学)
- 批准号:
8308251 - 财政年份:1983
- 资助金额:
$ 34.66万 - 项目类别:
Continuing Grant
Reactions and Stereochemistry of Organometallic Compounds Related to Asymmetric Synthesis and Catalytic Activity
与不对称合成和催化活性相关的有机金属化合物的反应和立体化学
- 批准号:
8208042 - 财政年份:1982
- 资助金额:
$ 34.66万 - 项目类别:
Continuing Grant
Reactions and Stereochemistry of Organometallic Compounds Related to Asymmetric Syntheses and Catalytic Activity
与不对称合成和催化活性相关的有机金属化合物的反应和立体化学
- 批准号:
7911201 - 财政年份:1979
- 资助金额:
$ 34.66万 - 项目类别:
Continuing Grant
Stereochemistry and Mechanisms of Organometallic Insertion And Rearrangement Reactions With Unsaturated Hydrocarbons
不饱和烃金属有机插入和重排反应的立体化学和机理
- 批准号:
7918188 - 财政年份:1979
- 资助金额:
$ 34.66万 - 项目类别:
Continuing Grant
Reactions and Stereochemistry of Organometallic Compounds Related to Asymmetric Syntheses and Catalytic Activity
与不对称合成和催化活性相关的有机金属化合物的反应和立体化学
- 批准号:
7714943 - 财政年份:1977
- 资助金额:
$ 34.66万 - 项目类别:
Continuing Grant
Reactions and Stereochemistry of Organometallic Compounds Related to Asymmetric Syntheses and Catalytic Activity
与不对称合成和催化活性相关的有机金属化合物的反应和立体化学
- 批准号:
7610762 - 财政年份:1976
- 资助金额:
$ 34.66万 - 项目类别:
Standard Grant