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New Functional Acrylates

New Functional Acrylates
新功能丙烯酸酯
批准号:
9111903
负责人:
Lon Mathias
金额:
$22.8万
依托单位国家:
美国
项目类别:
Continuing Grant
财政年份:
1991
资助国家:
美国
项目状态:
已结题
起止时间:
1991-11-01 至 1995-04-30
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This research deals with the chemistry of alpha- hydroxymethylacrylate (HMA) ester synthesis, polymerization, and characterization. Extension and exploration of the rich chemistry of various alkyl esters (RHMAs) will make available polymerizable derivatives possessing halide, ester, ether, silyl ether, urethane, and amine groups. Many of these will also possess siloxane, hydrocarbon, and fluorocarbon residues. Reactive oligomers with internal and terminal groups will be synthesized using a newly- discovered ether-forming reaction of the RHMA alcohol groups. Also available will be monomers with supernucleophilic catalyst groups, and monomers capable of forming polymerizable micelles, vesicles, monolayers, and liquid crystalline states. Cyclopolymerization of the ether dimers generates pyran-containing polymers with pendent carboxylate groups with potential anticancer and antiviral activity. Formation of reactive halides and isocyanates of the RHMA's extends the functional capability of the monomers and polymers to many other derivatives. Anionic and group transfer polymerizations of ethers and silyl ethers will allow isotactic and controlled MW polymer formation. Studies will also deal with intramolecular 6-membered ring hydrogen bond effects on polymer solubility and physical properties, steric inhibition of polymerization by a-methyl substituents, and use of the t-butyl effect to form high molecular weight cyclopolymers.
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URC Planning Grant for INSPIRE: Interstate Network of Science Programs Integrating Research and Education
  • 批准号:
    0418963
  • 项目类别:
    Standard Grant
  • 资助金额:
    $4.99万
  • 财政年份:
    2004
  • 负责人:
    Lon Mathias
  • 依托单位:
Second Annual Interstate Network of Science Programs Integrating Research and Education (INSPIRE) Undergraduate Research Conference; October 16-18, 2004; Hattiesburg, MS
  • 批准号:
    0442699
  • 项目类别:
    Standard Grant
  • 资助金额:
    $0.3万
  • 财政年份:
    2004
  • 负责人:
    Lon Mathias
  • 依托单位:
US-Turkey Cooperative Research: Functionalized Acrylates with Tailored Properties and Applications
  • 批准号:
    0218222
  • 项目类别:
    Continuing Grant
  • 资助金额:
    $7.0万
  • 财政年份:
    2002
  • 负责人:
    Lon Mathias
  • 依托单位:
REU Site: Doing Polymer Science with Collaborations at Four-Year Schools
  • 批准号:
    9988060
  • 项目类别:
    Continuing Grant
  • 资助金额:
    $22.55万
  • 财政年份:
    2000
  • 负责人:
    Lon Mathias
  • 依托单位:
国内基金
海外基金
Identification and quantification of primary phytoplankton functional types in the global oceans from hyperspectral ocean color remote sensing
  • 批准号:
    --
  • 项目类别:
    --
  • 资助金额:
    160万元
  • 批准年份:
    2022
  • 负责人:
    李忠平
  • 依托单位:
高维数据的函数型数据(functional data)分析方法
  • 批准号:
    11001084
  • 项目类别:
    青年科学基金项目
  • 资助金额:
    16.0万元
  • 批准年份:
    2010
  • 负责人:
    周迎春
  • 依托单位:
Multistage,haplotype and functional tests-based FCAR 基因和IgA肾病相关关系研究
  • 批准号:
    30771013
  • 项目类别:
    面上项目
  • 资助金额:
    30.0万元
  • 批准年份:
    2007
  • 负责人:
    王一鸣
  • 依托单位: