Bond-Forming Reactions at Transition Metal Centers

该项目由无机，生物无机和有机资助， 金属化学计划，分为五个领域： 1)线性配体（CO、CNR等）的还原偶联通过 早期过渡金属化合物，2）最近的化学 发现了顺磁性的三角双锥钴（III） 络合物，特别是可能的烷基衍生物， 3)使用新的铜和银的共轭加成化学 作为催化剂的配位络合物，4） 双核膦配体（大环配体，其中 一些供体是磷），和5）氧化偶联 反应，特别是水在多金属氧代络合物中的反应。 %%% 本项目的研究内容涉及 无机物的基本结构和反应性， 有机金属化合物 在这里获得的知识可能会 对一些领域的影响，包括催化、合成 精细化学品，生物分子的反应机理， 太阳能转换

This project, funded by the Inorganic, Bioinorganic and Organo- metallic Chemistry Program, is divided into five areas: 1) reductive coupling of linear ligands (CO, CNR, etc.) by early transition metal compounds, 2) chemistry of recently discovered paramagnetic, trigonal bipyramidal cobalt(III) complexes, and especially possible alkyl derivatives, 3) conjugate addition chemistry employing new copper and silver coordination complexes as catalysts, 4) metal complexes of binucleating phosphand ligands (macrocyclic ligands in which some donors are phosphorus), and 5) oxidative coupling reactions, especially of water, in polymetallic oxo complexes. %%% The research to be performed in this project is concerned with the fundamental structures and reactivities of inorganic and organometallic compounds. Knowledge obtained here will likely impact on a number of areas including catalysis, synthesis of fine chemicals, reaction mechanisms of biological molecules and solar energy conversion.